9,9-二辛基-2,7-二溴代芴合成路线 （共 30 条）
反应条件
sodium hydroxide in dimethyl sulfoxide T=20°C; 3 h;
参考文献
Keshtov; Mal'tsev; Lopatin; Nikitin; Blagodatskikh; Buzin; Pozin; Khokhlov
Doklady Chemistry, 2010 , vol. 432, # 2 p. 159 - 164
反应条件
bromine; iron(III) chloride in chloroform T=0 - 25°C; 24 h;
参考文献
Ranger, Maxime; Leclerc, Mario
Canadian Journal of Chemistry, 1998 , vol. 76, # 11 p. 1571 - 1577
反应条件
1: 85 percent / KOH / tetrahydrofuran / 20 °C 2: ferric chloride; bromine / CHCl3 / 3 h / 20 °C View Scheme
参考文献
Chemistry - A European Journal, , vol. 12, # 16 p. 4351 - 4361
反应条件
N-benzyl-N,N,N-triethylammonium chloride in water; dimethyl sulfoxide
参考文献
Sunaga, Tomoyasu
Patent: US2005/79382 A1, 2005 ;
反应条件
lithium diisopropyl amide
参考文献
Ego, Christophe; Marsitzky, Dirk; Becker, Stefan; Zhang, Jingying; Grimsdale, Andrew C.; Muellen, Klaus; MacKenzie, J. Devin; Silva, Carlos; Friend, Richard H.
Journal of the American Chemical Society, 2003 , vol. 125, # 2 p. 437 - 443
反应条件
1.1: n-butyllithium / tetrahydrofuran / -78 - 20 °C 1.2: 30.8 g / tetrahydrofuran / -78 - 20 °C 2.1: 90 percent / FeCl3; Br2 / CHCl3 / 3 h / 0 - 20 °C View Scheme
参考文献
Macromolecules, , vol. 37, # 11 p. 4087 - 4098
反应条件
potassium iodide; potassium hydroxide in dimethyl sulfoxide T=20°C; 24 h;
参考文献
Journal of Polymer Science, Part A: Polymer Chemistry, , vol. 51, # 4 p. 916 - 923
反应条件
1.1: Mg; iodine / tetrahydrofuran 1.2: tetrahydrofuran / -78 - 20 °C 2.1: 4.3 g / aq. H2SO4 / cooling 3.1: 72 percent / toluene / 10 h / Heating View Scheme
参考文献
Chen, Xiwen; Liao, Jin-Long; Liang, Yongmin; Ahmed; Tseng, Hao-En; Chen, Show-An
Journal of the American Chemical Society, 2003 , vol. 125, # 3 p. 636 - 637
反应条件
1: 2,7-dibromo-9,9-di-n-octylfluorene With magnesium in tetrahydrofuran 2: With boric acid trimethyl ester in tetrahydrofuran T=-70°C; 3: Trimethylene glycol Further stages;
参考文献
Chen, Run-Feng; Zhu, Rui; Fan, Qu-Li; Huang, Wei
Organic Letters, 2008 , vol. 10, # 13 p. 2913 - 2916
反应条件
1: 2,7-dibromo-9,9-di-n-octylfluorene With tert.-butyl lithium in tetrahydrofuran T=-78°C; 2: metaformaldehyde in tetrahydrofuran
参考文献
Intemann, Jeremy J.; Mike, Jared F.; Cai, Min; Bose, Sayantan; Xiao, Teng; Mauldin, Timothy C.; Roggers, Robert A.; Shinar, Joseph; Shinar, Ruth; Jeffries-El, Malika
Macromolecules, 2011 , vol. 44, # 2 p. 248 - 255
