9,9-二辛基-2,7-二溴代芴合成路线 （共 30 条）
反应条件
potassium carbonate; Pd(0)(PPh3)4 in toluene
反应条件
1: With n-butyllithium in tetrahydrofuran; hexane T=0°C; 2: With methanol in tetrahydrofuran; hexane T=0°C;
参考文献
Organic Letters, , vol. 10, # 18 p. 3937 - 3940
反应条件
1: in tetrahydrofuran; hexane T=0°C; 0.166667 h; 2: With methanol in tetrahydrofuran; hexane T=-78°C; 0.166667 h;
参考文献
Organic Letters, , vol. 10, # 18 p. 3937 - 3940
反应条件
1: With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 4.5 h; Inert atmosphere; 2: With tri-isopropoxy-borane in tetrahydrofuran; hexane T=-78 - 20°C; Inert atmosphere;
参考文献
Zhu, Haifeng; Tong, Hui; Gong, Yongyang; Shao, Shiyang; Deng, Chunmei; Yuan, Wang Zhang; Zhang, Yongming
Journal of Polymer Science, Part A: Polymer Chemistry, 2012 , vol. 50, # 11 p. 2172 - 2181
反应条件
1: tris-(dibenzylideneacetone)dipalladium(0); 2,2'-bis-(diphenylphosphino)-1,1'- binaphthyl; sodium t-butanolate / toluene / 12 h / 80 °C / Inert atmosphere
2: hydrogenchloride; water / tetrahydrofuran / 8 h / 23 °C / Inert atmosphere
View Scheme
参考文献
Rostami, Ali; Guerin, Gerald; Taylor, Mark S.
Macromolecules, 2013 , vol. 46, # 16 p. 6439 - 6450
反应条件
1.1: n-BuLi / diethyl ether / -78 - 20 °C
1.2: 90 percent / diethyl ether / -78 - 20 °C
2.1: SOCl2 / Heating
View Scheme
参考文献
Ding, Jianfu; Day, Michael; Robertson, Gilles; Roovers, Jacques
Macromolecules, 2002 , vol. 35, # 9 p. 3474 - 3483
反应条件
1: 2,7-dibromo-9,9-di-n-octylfluorene With tert.-butyl lithium in tetrahydrofuran; pentane
T=-78°C;
2: N,N-dimethyl-formamide in tetrahydrofuran; pentane
T=-78 - 20°C;
参考文献
Maji, Modhu Sudan; Pfeifer, Thorben; Studer, Armido
Chemistry - A European Journal, 2010 , vol. 16, # 20 p. 5872 - 5875
反应条件
1: tert.-butyl lithium / tetrahydrofuran / -78 °C
2: manganese(IV) oxide / benzene
View Scheme
参考文献
Intemann, Jeremy J.; Mike, Jared F.; Cai, Min; Barnes, Charles A.; Xiao, Teng; Roggers, Robert A.; Shinar, Joseph; Shinar, Ruth; Jeffries-El, Malika
Journal of Polymer Science, Part A: Polymer Chemistry, 2013 , vol. 51, # 4 p. 916 - 923
反应条件
1: 2,7-dibromo-9,9-di-n-octylfluorene With n-butyllithium in tetrahydrofuran
T=-78 - 20°C;
2: N,N-dimethyl-formamide in tetrahydrofuran
T=-78 - 20°C;
参考文献
Zhou, Huipeng; Zhao, Xin; Huang, Tianhao; Lu, Ran; Zhang, Hanzhuang; Qi, Xiaohui; Xue, Pengchong; Liu, Xingliang; Zhang, Xiaofei
Organic and Biomolecular Chemistry, 2011 , vol. 9, # 5 p. 1600 - 1607
反应条件
1: 2,7-dibromo-9,9-di-n-octylfluorene With n-butyllithium in diethyl ether; hexane
T=-10°C; 3 h;
2: chloro-trimethyl-silane in diethyl ether; hexane
T=20°C; Further stages.;
参考文献
Jeeva, Shezhad; Moratti, Stephen C.
Synthesis, 2007 , # 21 art. no. P08807SS, p. 3323 - 3328
