6-乙酰基-5-羟基-7-甲基-1,4-萘醌合成路线 （共 8 条）
反应条件
potassium hydroxide in methanol; water 0.05 h; Ambient temperature;
参考文献
Rizzacasa, Mark A.; Sargent, Melvyn V.
Australian Journal of Chemistry, 1988 , vol. 41, # 7 p. 1087 - 1097
反应条件
1: 71 percent / CaCO3 / acetone / 3.75 h / Heating 2: LiAlH4 / tetrahydrofuran / 1 h / Ambient temperature 3: H2, conc. HCl / 10percent Pd/C / ethanol 5: 89 percent / BF3*Et2O / 0.75 h / 60 °C 6: pyridine / 18 h / Ambient temperature 7: 1.) AgO, 2.) nitric acid / 1.) dioxan, 5 min, 2.) 5 min 8: 65 percent / KOH / methanol; H2O / 0.05 h / Ambient temperature View Scheme
参考文献
Rizzacasa, Mark A.; Sargent, Melvyn V.
Australian Journal of Chemistry, 1988 , vol. 41, # 7 p. 1087 - 1097
反应条件
1: 70 percent / H2, CaCO3 / 10percent Pd/C / methanol / 3 h View Scheme
参考文献
Laatsch, Hartmut
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1986 , vol. 41, # 3 p. 377 - 385
反应条件
2: 89 percent / BF3*Et2O / 0.75 h / 60 °C 3: pyridine / 18 h / Ambient temperature 4: 1.) AgO, 2.) nitric acid / 1.) dioxan, 5 min, 2.) 5 min 5: 65 percent / KOH / methanol; H2O / 0.05 h / Ambient temperature View Scheme
参考文献
Rizzacasa, Mark A.; Sargent, Melvyn V.
Australian Journal of Chemistry, 1988 , vol. 41, # 7 p. 1087 - 1097
反应条件
1: 89 percent / BF3*Et2O / 0.75 h / 60 °C 2: pyridine / 18 h / Ambient temperature 3: 1.) AgO, 2.) nitric acid / 1.) dioxan, 5 min, 2.) 5 min 4: 65 percent / KOH / methanol; H2O / 0.05 h / Ambient temperature View Scheme
参考文献
Rizzacasa, Mark A.; Sargent, Melvyn V.
Australian Journal of Chemistry, 1988 , vol. 41, # 7 p. 1087 - 1097
反应条件
1: pyridine / 18 h / Ambient temperature 2: 1.) AgO, 2.) nitric acid / 1.) dioxan, 5 min, 2.) 5 min 3: 65 percent / KOH / methanol; H2O / 0.05 h / Ambient temperature View Scheme
参考文献
Rizzacasa, Mark A.; Sargent, Melvyn V.
Australian Journal of Chemistry, 1988 , vol. 41, # 7 p. 1087 - 1097
反应条件
1: 1.) AgO, 2.) nitric acid / 1.) dioxan, 5 min, 2.) 5 min 2: 65 percent / KOH / methanol; H2O / 0.05 h / Ambient temperature View Scheme
参考文献
Rizzacasa, Mark A.; Sargent, Melvyn V.
Australian Journal of Chemistry, 1988 , vol. 41, # 7 p. 1087 - 1097
反应条件
Yield given. Multistep reaction;
参考文献
Laatsch, Hartmut
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1986 , vol. 41, # 3 p. 377 - 385
