2,2-二氯双环[2.2.1]庚烷合成路线 (共 2 条)
反应条件
phosphorus pentachloride; phosphorus trichoride Ambient temperature;
参考文献
Ashby, E. C.; Sun, Xiaojing; Duff, J. L.
Journal of Organic Chemistry, 1994 , vol. 59, # 6 p. 1270 - 1278
反应条件
1: 85 g / SnCl4 / toluene
2: 51 g / t-BuOK / dimethylsulfoxide / Ambient temperature
3: 16 g / HCl / CH2Cl2 / -78 °C
4: 4.7 g / AgNO3 / dioxane; H2O / 39 h / Heating
5: 41 g / Brown's reagent / diethyl ether / 24 h / Ambient temperature
View Scheme
参考文献
Werstiuk, Nick Henry; Dhanoa, Daljit; Timmins, George
Canadian Journal of Chemistry, 1983 , vol. 61, p. 2403 - 2414