199620-14-9合成路线 （共 107 条）
反应条件
in tetrahydrofuran Irradiation (UV/VIS);
参考文献
Strohmeier, W.; Guttenberger, J. F.; Blumenthal, H.; Albert, G.
Chemische Berichte, 1966 , vol. 99, p. 3419 - 3424
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Gmelin Handbook: Cr: Org.Verb., 1.1.2.1.4.1, page 41 - 54
反应条件
tetra-n-butylammonium tetrafluoroborate; triphenylphosphine in tetrahydrofuran Electrochem. Process; ligand:Cr(CO)6 1:1, electrolysis for 8 h at room temp. in an autoclave under N2; the volatiles are evapd.;
参考文献
Grobe, Joseph; Zimmermann, Heinz
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1981 , vol. 36, # 3 p. 301 - 306
反应条件
in further solvent(s) mole ratio of educts 1:1, at boiling temp. or in bomb tube at 130-190°C; solvent diglycole dimethyl ether or other solvents of sufficiently high boiling point;;
参考文献
Gmelin Handbook: Cr: Org.Verb., 1.1.2.1.4.2, page 54 - 62
反应条件
triphenylphosphine in further solvent(s) Kinetics; byproducts: CO; Sonication; in different alkanes;
参考文献
Suslick, Kenneth S.; Goodale, James W.; Schubert, Paul F.; Wang, Hau H.
Journal of the American Chemical Society, 1983 , vol. 105, # 18 p. 5781 - 5785
反应条件
triphenylphosphine in acetonitrile under N2, addn. of TMNO dihydrate to carbonyl-compd. in CH3CN at 0°C, addn. of PPh3 after stirring for 10 min, stirred for 16 h at 0°C; evapn. under vac., filtration, recrystn. (CH2Cl2/CH3OH or CH2Cl2/hexane); elem. anal.;
参考文献
Hor, T. S. Andy
Inorganica Chimica Acta, 1988 , vol. 143, p. 3 - 6
反应条件
triphenylphosphine in dichloromethane Kinetics; byproducts: CO2, (CH3)3N; (N2); at 14.5 °C; react. in soln. monitored IR and UV spect.; react. mechanism discussed; not isolated;
参考文献
Shi, Yan-Lung; Gao, Yi-Ci; Shi, Qi-Zhen; Kershner, David L.; Basolo, Fred
Organometallics, 1987 , vol. 6, p. 1528 - 1531
反应条件
in acetonitrile Preparation under dry nitrogen; Cr(CO)6 and TMNO were added to acetonitrile giving a yellow solution; PPh3 was added, stirring at room temperature for 16h; filtration; filtrate was cooled at -20°C; recrystallization in CHCl3/EtOH; DSC, TG, elem. anal.;
参考文献
Hor, T. S. Andy; Chan, Hardy S. O.; Chiam, Caroline S. M.; Lim, Kok Hwa
Thermochimica Acta, 1988 , vol. 128, p. 175 - 184
反应条件
in tetrahydrofuran a soln. of tungsten hexacarbonyl was treated with sulfilimine in the presence of excess of PPh3;
参考文献
Raubenheimer, Helgard G.; Kruger, Gert J.; Scott, Fred; Otte, Ronald
Organometallics, 1987 , vol. 6, p. 1789 - 1795
反应条件
in not given byproducts: CO2, NH3; NH2OH and PPh3 addn. simultaneously into M(CO)6 soln. at room temp., reaction mixt. allowing to stand for a few h after reaction with NH2OH hascompleted; IR spectroscopic monitoring;
参考文献
Maksakov, V. A.; Ershova, V. A.
Journal of Organometallic Chemistry, 1995 , vol. 485, # 1-2 p. 69 - 78
反应条件
in decane; cyclohexane Kinetics; at 122.5 .+-. 0.3 °C.;
参考文献
Gmelin Handbook: Cr: Org.Verb., 1.1.2.1.5.2, page 66 - 70
