199620-14-9合成路线 （共 107 条）
反应条件
tetrahydrofuran; aniline in tetrahydrofuran Irradiation (UV/VIS); Cr(CO)6 was irradiated in THF at 0°C under N2 until max. possible amt. of (CO)5Cr(THF) was formed (IR control), resulting soln. was treated at 20°C with an equimol. amt. of aniline; volatiles were removed under high vac., residue taken up in toluene, filtered, petroleum ether was added to the filtrate, cooled to -78°C, resulting crystals were filtered, washed with cold hexane, dried under high vac. for 8 h; elem. anal.;
参考文献
Sellmann, Dieter; Mueller, Juergen
Journal of Organometallic Chemistry, 1984 , vol. 277, # 3 p. 379 - 394
反应条件
Irradiation (UV/VIS);
参考文献
Strohmeier, W.
Zeitschrift fuer Naturforschung, 1964 , vol. 19b, p. 540 - 540
Full Text Show Details
Gmelin Handbook: Cr: Org.Verb., 1.1.2.1.4.1, page 41 - 54
反应条件
(i), (ii) /BRN= 3597303/, (iii) 2,3-dimethyl-but-2-ene (heating); Multistep reaction;
参考文献
Fischer,E.O. et al.
Journal of Organometallic Chemistry, 1969 , vol. 16, p. P29 - P32
反应条件
in neat (no solvent, gas phase) Kinetics; Sb2(1-) formation by laser ablation of Sb-sample;
参考文献
Arnold Jr., Frederick P.; Ridge, Douglas P.; Rheingold, Arnold L.
Journal of the American Chemical Society, 1995 , vol. 117, # 15 p. 4427 - 4428
反应条件
KC8 in tetrahydrofuran add. of Cr(CO)6 to a suspension of KC8 under Ar at -70°C, stirring (-70°C, 1 h; 0°C, 2 h), addn. of anhydr. SnCl2 at -70°C, addn. of cryptand after 0.5 h stirring, warming to 0°C; filtn. through Kieselgur, concg. in high-vac., layering (15°C, Et2O, pentane), after 7 days Sn seperates;
参考文献
Schiemenz, Berthold; Huttner, Gottfried
Angewandte Chemie, 1993 , vol. 105, p. 295 - 296
反应条件
carbon monoxide under pressure;
参考文献
Gmelin Handbook: Cr: Org.Verb., 1.6.1.2.2.12, page 240 - 243
反应条件
in gas byproducts: CO; Irradiation (UV/VIS); at room temp.; photodissocn. by dye laser; not isolated, detected by multiphoton ionization spectroscopy;
参考文献
Owen, B. B.; Webber, R. T.
Trans. Am. Inst. Min., Metall. Pet. Eng., 1948 , vol. 175, p. 693 - 698
反应条件
in neat (no solvent) decompn. of Cr(CO)6 in H2 at 450-625 °C, 0.04-0.22 Torr;; film;;
参考文献
Gmelin Handbook: Cr: MVol.B, 175, page 361 - 363
反应条件
in neat (no solvent) thermal decompn. at 503-613 K;
参考文献
Mikami, Naohiko; Ohki, Rie; Kido, Hiroaki
Chemical Physics, 1988 , vol. 127, p. 161 - 172
反应条件
in tetrahydrofuran Irradiation (UV/VIS); A soln. of nitroso compound in THF under N2 is stirred until it becomes light blue, to this soln. is added metal carbonyl, the soln. is irradiated (sunlamp photolysis) for a period of 4 h at 30°C.; reaction mixture is cooled to 25°C, the solvent is removed, purifn. by chromy. on silica gel using 19/1 hexane/ethyl acetate as eluent;
参考文献
Herndon, James W.; McMullen, Leonard A.
Journal of Organometallic Chemistry, 1989 , vol. 368, p. 83 - 102
