1,2-二(二苯基膦基)乙烷二氯化钯(II)合成路线 （共 27 条）
反应条件
in benzene pptd. PdCl2(dppe) filtered off; filtrate concd., hexane added, crystalsof bis(aldoximato) complex collected, washed with hexane, dried in air;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 1698 - 1702
反应条件
in benzene stirring at 298 K for 10 min; pptd. PdCl2(dppe) collected by filtration, bis-aldoximato complex obtained from green filtrate;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 1698 - 1702
反应条件
in chloroform-d1 mixing at 240 K, standing; not sepd.; NMR spectroscopy;
参考文献
Polyhedron, , vol. 18, # 20 p. 2583 - 2595
反应条件
in chloroform-d1 40°C, 30 min;
参考文献
Dalton Transactions, , # 12 p. 2210 - 2216
反应条件
NH3 in ammonia NH3 (liquid); inert atmosphere;
参考文献
O'Mahoney, Caroline A.; Parkin, Ivan P.; Williams, David J.; Woollins, J. Derek
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1989 , p. 1179 - 1186
反应条件
KF; 18-crown-6 in tetrahydrofuran; pyridine byproducts: Ph2PCH2CH2P(O)Ph2, Ph2PCH2CH2PF2Ph2; heating a suspn. of (dppe)PdCl2, dppe, anhyd. KF and 18-crown-6 in pyridine/THF under Ar (100°C, 2 h); not separated and isolated; 65 percent yield of the difluorophosphorane product of the total oxidn. products; detn. by 31P-NMR;
参考文献
Organometallics, , vol. 11, p. 2212 - 2220
反应条件
1: toluene 2: tetrahydrofuran; THF-d8 (tetrahydrofuran-d8) View Scheme
参考文献
European Journal of Inorganic Chemistry, , # 11 p. 2868 - 2877
