(E)-三甲基(1-苯基-1-丙烯-2-基氧基)硅烷合成路线 （共 11 条）
反应条件
sodium hydride; triethylamine in diethyl ether 1.) reflux, 2 h, 2.) 0 deg C; Yield given. Yields of byproduct given;
参考文献
Gaudemar, Marcel; Bellassoued, Moncef
Tetrahedron Letters, 1989 , vol. 30, # 21 p. 2779 - 2782
反应条件
1: diazomethyl-trimethyl-silane With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 1 h; 2: acetophenone With methanol in tetrahydrofuran; hexane T=-78°C; 0.833333 h; 3: With dirhodium tetraacetate in tetrahydrofuran T=-78 - 20°C; Further stages. Title compound not separated from byproducts.;
参考文献
Kang, Byung Chul; Shim, Su Yong; Ryu, Do Hyun
Organic Letters, 2014 , vol. 16, # 8 p. 2077 - 2079
反应条件
ethylaluminum dichloride in dichloromethane T=-40°C; 0.5 h;
参考文献
Kang, Byung Chul; Shim, Su Yong; Ryu, Do Hyun
Organic Letters, 2014 , vol. 16, # 8 p. 2077 - 2079
反应条件
(i) LDA, 1,2-dimethoxyethane, (ii) /BRN= 1209232/, Et3N; Multistep reaction;
参考文献
Rathore, Rajendra; Kochi, Jay K.
Journal of Organic Chemistry, 1996 , vol. 61, # 2 p. 627 - 639
反应条件
tri-t-butylphenyllithium; triethylamine in tetrahydrofuran T=-97°C; 0.5 h; further base reagents and temperatures; Product distribution;
参考文献
Davis, Franklin A.; Sheppard, Aurelia C.; Chen, Bang-Chi; Haque, M. Serajul
Journal of the American Chemical Society, 1990 , vol. 112, # 18 p. 6679 - 6690
反应条件
triethylamine; sodium iodide in acetonitrile; pentane 15 min, room temp.; 4 h, 40 deg C; Yield given. Yields of byproduct given;
参考文献
Cazeau, P.; Duboudin, F.; Moulines, F.; Babot, O.; Dunogues, J.
Tetrahedron, 1987 , vol. 43, # 9 p. 2075 - 2088
反应条件
in chloroform T=20 - 25°C; 1.5 h; Yield given. Yields of byproduct given;
参考文献
Anders, Ernst; Stankowiak, Achim; Riemer, Roland
Synthesis, 1987 , # 10 p. 931 - 934
反应条件
tetrabutylammonium fluoride absorbed on silica gel in tetrahydrofuran 3.5 h; Ambient temperature;
参考文献
Gambacorta, Augusto; Turchetta, Stefano; Botta, Maurizio
Synthetic Communications, 1989 , vol. 19, # 13-14 p. 2441 - 2448
反应条件
pyrrolidin-2-one; tetraethylammonium tetrafluoroborate 1.) DME, HMPA, RT, electrochemical reduction, 2.) DME, HMPA, -75 deg C, 1 h; Yield given. Multistep reaction. Title compound not separated from byproducts;
参考文献
Bonafoux, Dominique; Bordeau, Michel; Biran, Claude; Dunogues, Jacques
Journal of Organometallic Chemistry, 1995 , vol. 493, # 1-2 p. 27 - 32
反应条件
sodium hydroxide; formic acid; water; sodium chloride in acetonitrile T=25°C; Rate constantMechanism;
参考文献
Novice, Marilyn H.; Seikaly, Hani R.; Seiz, Annette D.; Tidwell, Thomas T.
Journal of the American Chemical Society, 1980 , vol. 102, # 18 p. 5835 - 5838
