1-(三甲基硅氧基)环戊烯合成路线 （共 155 条）
反应条件
tris(pentafluorophenyl)-borane; hydrogen; dppn in benzene
T=20°C; P=1500.15 Torr; 20 h;
参考文献
Wang, Huadong; Froehlich, Roland; Kehr, Gerald; Erker, Gerhard
Chemical Communications, 2008 , # 45 p. 5966 - 5968
反应条件
[VO(OEt)Cl2] in dichloromethane
T=-75°C;
参考文献
Hirao, Toshikazu; Fujii, Takashi; Ohshiro, Yoshiki
Tetrahedron, 1994 , vol. 50, # 34 p. 10207 - 10214
反应条件
ammonium cerium(IV) nitrate; sodium hydrogencarbonate in acetonitrile
0.0833333 h; Ambient temperature;
参考文献
Baciocchi, Enrico; Casu, Angela; Ruzziconi, Renzo
Tetrahedron Letters, 1989 , vol. 30, # 28 p. 3707 - 3710
反应条件
(i) CH2Cl2, SnCl4, (ii) H2O; Multistep reaction;
参考文献
Miyashita,M. et al.
Journal of the American Chemical Society, 1976 , vol. 98, p. 4679 - 4681
反应条件
bromine in dichloromethane
参考文献
Zembayashi,M. et al.
Synthesis, 1977 , p. 422 - 423
反应条件
chloramine-T
1.) CH2Cl2, -12 deg C, 2.) CH2Cl2, -25 deg C, 30 min; Yield given. Multistep reaction;
参考文献
Magnus, Philip; Rigollier, Pascal
Tetrahedron Letters, 1992 , vol. 33, # 41 p. 6111 - 6114
参考文献
Ryu,I. et al.
Synthesis, 1977 , p. 874 - 876
反应条件
[TiCl(isopropoxy)3]; N,N,N',N',N'',N''-hexamethylphosphoric triamide; methyllithium
1.) ether, RT, 2.) THF, -50 deg C, 10 h; Yield given. Multistep reaction;
参考文献
Hernandez, Rosendo; Melian, Daniel; Prange, Thierry; Suarez, Ernesto
Heterocycles, 1995 , vol. 41, # 3 p. 439 - 454
反应条件
1: (1-cyclopentene-l-yl-oxy)-trimethylsilane With nonafluoro-n-butanesulfonyl fluoride; tetrabutyl ammonium fluoride in tetrahydrofuran
T=20°C; 16 h;
2: acrylic acid methyl ester With palladium diacetate; tetrabutyl-ammonium chloride; potassium carbonate in N,N-dimethyl-formamide
T=25°C; 6 h;
参考文献
Lyapkalo, Ilya M.; Webel, Matthias; Reissig, Hans-Ulrich
European Journal of Organic Chemistry, 2002 , # 21 p. 3646 - 3658
反应条件
sodium tris(acetoxy)borohydride; acetic acid in 1,2-dichloro-ethane
T=20°C; 2 h;
参考文献
Reddy, T. Jagadeeswar; Leclair, Michael; Proulx, Melanie
Synlett, 2005 , # 4 art. no. S07004ST, p. 583 - 586
