1-(三甲基硅氧基)环戊烯合成路线 (共 155 条)
反应条件
T=110°C; ΔH(activation), ΔS(activation), ΔG(activation) for 350 deg C; Thermodynamic dataKineticsRate constant;
参考文献
Journal of Organic Chemistry, , vol. 46, # 3 p. 506 - 509
反应条件
Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Prieto, J. Antonio; Larson, Gerald L.
Synthetic Communications, 1980 , vol. 10, # 9 p. 675 - 684
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; methyllithium; dimethyl zinc in tetrahydrofuran T=-78°C; 10 h;
参考文献
Morita, Yasushi; Suzuki, Masaaki; Noyori, Ryoji
Journal of Organic Chemistry, 1989 , vol. 54, # 8 p. 1785 - 1787
反应条件
methyllithium in tetrahydrofuran T=0°C; 3 h; Further byproducts given;
参考文献
Morita, Yasushi; Suzuki, Masaaki; Noyori, Ryoji
Journal of Organic Chemistry, 1989 , vol. 54, # 8 p. 1785 - 1787
反应条件
methyllithium in tetrahydrofuran T=0°C; 3 h; var. temp., times, and reagent systems; other lithium enolates; Product distribution;
参考文献
Morita, Yasushi; Suzuki, Masaaki; Noyori, Ryoji
Journal of Organic Chemistry, 1989 , vol. 54, # 8 p. 1785 - 1787
反应条件
methyl lithium LiBr complex; dimethyl zinc 1.) THF, rt, 1 h, 2.) HMPA, THF, -78 deg C, 15 h; Yield given. Multistep reaction;
参考文献
Broeders, F.; Braekman, J. C.; Daloze, D.
Bulletin des Societes Chimiques Belges, 1997 , vol. 106, # 7-8 p. 377 - 382
反应条件
Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Prieto, J. Antonio; Larson, Gerald L.
Synthetic Communications, 1980 , vol. 10, # 9 p. 675 - 684
反应条件
TNM in pentane 5 h; Ambient temperature;
参考文献
Rathore, Rajendra; Lin, Zhe; Kochi, Jay K.
Tetrahedron Letters, 1993 , vol. 34, # 12 p. 1859 - 1862
反应条件
in dichloromethane 5 h; Ambient temperature;
参考文献
Rathore, Rajendra; Kochi, Jay K.
Journal of Organic Chemistry, 1996 , vol. 61, # 2 p. 627 - 639
反应条件
tetrachlorosilane; mercury(II) diacetate in dichloromethane T=20°C; metathesis reaction; 10 h;
参考文献
Denmark, Scott E.; Stavenger, Robert A.; Winter, Stephen B. D.; Wong, Ken-Tsung; Barsanti, Paul A.
Journal of Organic Chemistry, 1998 , vol. 63, # 25 p. 9517 - 9523