1-(三甲基硅氧基)环戊烯合成路线 （共 155 条）
反应条件
(CF3CH2O)VOCl2 T=-78°C; 0.5 h;
参考文献
Ryter; Livinghouse
Journal of the American Chemical Society, 1998 , vol. 120, # 11 p. 2658 - 2659
反应条件
silyl enol ether; [VO(OEt)Cl2] T=-78 - -40°C; 7 h;
参考文献
Ryter; Livinghouse
Journal of the American Chemical Society, 1998 , vol. 120, # 11 p. 2658 - 2659
反应条件
[VO(OEt)Cl2] in dichloromethane 1) -75 deg C, 3 h, 2) -30 deg C, 4 h;
参考文献
Fujii Takashi; Hirao, Toshikazu; Ohshiro, Yoshiki
Tetrahedron Letters, 1992 , vol. 33, # 39 p. 5823 - 5826
反应条件
bismuth(III) chloride; sodium iodide in diethyl ether; dichloromethane 0.333333 h; Ambient temperature;
参考文献
Journal of Organic Chemistry, , vol. 61, # 11 p. 3885 - 3887
反应条件
boron trifluoride in nitromethane T=-35°C; 1 h;
参考文献
Kopka, Ihor; Rathke, Michael W.
Journal of Organic Chemistry, 1981 , vol. 46, # 19 p. 3771 - 3773
反应条件
antimony trichloride in dichloromethane T=0°C; 1 h;
参考文献
Journal of Organic Chemistry, , vol. 47, # 26 p. 5099 - 5102
反应条件
1: (1-cyclopentene-l-yl-oxy)-trimethylsilane With methyllithium in diethyl ether T=0°C; Inert atmosphere; 2: PhOCN in ethylene glycol dimethyl ether; diethyl ether T=-70°C; 8 h; Inert atmosphere;
参考文献
Buttke, Klaus; Niclas, Hans-Joachim
Journal fuer Praktische Chemie/Chemiker-Zeitung, 1998 , vol. 340, # 7 p. 669 - 675
反应条件
1: (1-cyclopentene-l-yl-oxy)-trimethylsilane With methyllithium in diethyl ether T=0°C; Inert atmosphere; 2: 1-naphthyl cyanate in ethylene glycol dimethyl ether; diethyl ether T=-70°C; 8 h; Inert atmosphere;
参考文献
Buttke, Klaus; Niclas, Hans-Joachim
Journal fuer Praktische Chemie/Chemiker-Zeitung, 1998 , vol. 340, # 7 p. 669 - 675
反应条件
1: 89 percent / ZnBr2 / CH2Cl2 / 2 h / Ambient temperature
2: 1.) MCPBA / 1.) 0 deg C, 0.5 h, 2.) toluene, 100 deg C, 4 h
3: 62 percent / HCl / methanol; H2O / 8 h / Heating
View Scheme
参考文献
Ono, Noboru; Miyake, Hideyoshi; Kaji, Aritsume
Synthesis, 1981 , # 12 p. 1003 - 1004
反应条件
1: (1-cyclopentene-l-yl-oxy)-trimethylsilane With nonafluoro-n-butanesulfonyl fluoride; tetrabutyl ammonium fluoride in tetrahydrofuran
T=20°C; 16 h;
2: styrene With palladium diacetate; potassium acetate; potassium carbonate in N,N-dimethyl-formamide
T=85°C; 6 h;
参考文献
Lyapkalo, Ilya M.; Webel, Matthias; Reissig, Hans-Ulrich
European Journal of Organic Chemistry, 2002 , # 21 p. 3646 - 3658
