4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-十七氟十一烷基碘合成路线 (共 7 条)
→
200112-75-04,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-十七氟十一烷基碘
反应条件
phosphoric acid; phosphorus pentoxide; potassium iodide
参考文献
Vincent, Jean-Marc; Rabion, Alain; Yachandra, Vittal K.; Fish, Richard H.
Angewandte Chemie, International Edition in English, 1997 , vol. 36, # 21 p. 2346 - 2349
Angewandte Chemie, 1997 , vol. 109, p. 2438 - 2440
→
200112-75-04,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-十七氟十一烷基碘
反应条件
1: 76 percent / LiAlH4 / tetrahydrofuran 2: 76 percent / PPh3; I2; imidazole / CH2Cl2 / 0 - 20 °C View Scheme
参考文献
Vincent, Jean-Marc; Rabion, Alain; Yachandra, Vittal K.; Fish, Richard H.
Angewandte Chemie, International Edition in English, 1997 , vol. 36, # 21 p. 2346 - 2349
Angewandte Chemie, 1997 , vol. 109, p. 2438 - 2440
→
200112-75-04,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-十七氟十一烷基碘
反应条件
1: AIBN / 75 °C 2: 76 percent / LiAlH4 / tetrahydrofuran 3: 76 percent / PPh3; I2; imidazole / CH2Cl2 / 0 - 20 °C View Scheme
参考文献
Sinou, Denis; Pozzi, Gianluca; Hope, Eric G.; Stuart, Alison M.
Tetrahedron Letters, 1999 , vol. 40, # 5 p. 849 - 852
200112-75-04,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-十七氟十一烷基碘
→
139175-50-14,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-十七氟十一胺
反应条件
ammonia in tetrahydrofuran T=25°C; 24 h;
参考文献
Szlavik, Zoltan; Tarkanyi, Gabor; Goemoery, Agnes; Tarczay, Gyoergy; Rabai, Jozsef
Journal of Fluorine Chemistry, 2001 , vol. 108, # 1 p. 7 - 14
200112-75-04,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-十七氟十一烷基碘
→
139175-50-14,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-十七氟十一胺
反应条件
1.1: 80 percent / dimethylformamide / 7 h / 100 °C 2.1: hydrazine hydrate / methanol / 1 h / Heating 2.2: 77 percent / aq. HCl / methanol / 1 h / 32 View Scheme
参考文献
Abulikemu, Abudurexiti; Halasz, Gabor; Csampai, Antal; Goemoery, Agnes; Rabai, Jozsef
Journal of Fluorine Chemistry, 2004 , vol. 125, # 7 p. 1143 - 1146
200112-75-04,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-十七氟十一烷基碘
→
反应条件
C49H34F68N(1+)*I(1-) in 1-perfluoromethyldecaline; water T=100°C; Finkelstein type reaction; 24 h;
参考文献
Mandal, Debaprasad; Gladysz, John A.
Tetrahedron, 2010 , vol. 66, # 5 p. 1070 - 1077
200112-75-04,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-十七氟十一烷基碘
→
494798-73-14-[(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-十七氟十一烷基)氧基]苯甲醛
反应条件
potassium carbonate in DMF (N,N-dimethyl-formamide)
T=65°C;
参考文献
FLUOROUS TECHNOLOGIES INCORPORATED
Patent: WO2004/7407 A2, 2004 ;
Location in patent: Page 50 ;