(Z)-2-甲基-2-丁烯腈合成路线 (共 29 条)
反应条件
bidentate phosphite ligand:Ni(0) HeatingGas phase; Product distribution / selectivity;
参考文献
INVISTA TECHNOLOGIES S.A. R.L.; MOERBE, Larry, E.; CHAO, Tseng, H.
Patent: WO2012/5910 A1, 2012 ;
Location in patent: Page/Page column 54; 89-93 ;
参考文献
Ioffe,B.V.; Zelenina,N.L.
Zhurnal Organicheskoi Khimii, 1968 , vol. 4, # 9 p. 1558 - 1561,1496 - 1499
反应条件
zinc(II) chloride; 1,1'-bis-(diphenylphosphino)ferrocene; bis(1,5-cyclooctadiene)nickel (0) T=100°C; 2.5 h; Product distribution; Further Variations:CatalystsReagents;
参考文献
Acosta-Ramirez, Alberto; Munoz-Hernandez, Miguel; Jones, William D.; Garcia, Juventino J.
Journal of Organometallic Chemistry, 2006 , vol. 691, # 18 p. 3895 - 3901
反应条件
pyridine; trichlorophosphate
参考文献
Heilmann et al.
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1957 , vol. 244, p. 1787
参考文献
Bruylants; Ernould; Dekoker
Bulletin des Societes Chimiques Belges, 1930 , vol. 39, p. 386,389,391
Bulletin de la Classe des Sciences, Academie Royale de Belgique, 1930 , vol. <5>16, p. 730,734,736
反应条件
C48H52O4P2; (m-tolyl-O-)(p-tolyl-O-)2P; (m-tolyl-O-)2(p-tolyl-O-)P; tri(m-methylphenyl) phosphite; tri-p-tolyl phosphite T=83.84°C; Product distribution / selectivity;
参考文献
BASF AKTIENGESELLSCHAFT
Patent: WO2005/73175 A1, 2005 ;
Location in patent: Page/Page column 36-39; sheet 1 ;
反应条件
C48H52O4P2; (m-tolyl-O-)(p-tolyl-O-)2P; (m-tolyl-O-)2(p-tolyl-O-)P; tri(m-methylphenyl) phosphite; tri-p-tolyl phosphite T=99.84°C; Product distribution / selectivity;
参考文献
BASF AKTIENGESELLSCHAFT
Patent: WO2005/73171 A1, 2005 ;
Location in patent: Page/Page column 38-41; sheet 6 ;
反应条件
1: With C48H52O4P2; (m-tolyl-O-)(p-tolyl-O-)2P; (m-tolyl-O-)2(p-tolyl-O-)P; tri(m-methylphenyl) phosphite; tri-p-tolyl phosphite T=83.84°C; 2: T=119.84°C; Product distribution / selectivity;
参考文献
BASF AKTIENGESELLSCHAFT
Patent: WO2005/73174 A1, 2005 ;
Location in patent: Page/Page column 76-80; sheet 3 ;
反应条件
1: With C42H40O6P2; (m-tolyl-O-)(p-tolyl-O-)2P; (m-tolyl-O-)2(p-tolyl-O-)P; tri(m-methylphenyl) phosphite; tri-p-tolyl phosphite T=99.84°C; 2: With nickel T=109.84°C; Product distribution / selectivity;
参考文献
BASF AKTIENGESELLSCHAFT
Patent: WO2005/73174 A1, 2005 ;
Location in patent: Page/Page column 86-89; sheet 4 ;
反应条件
1: With C44H44O6P2; (m-tolyl-O-)(p-tolyl-O-)2P; (m-tolyl-O-)2(p-tolyl-O-)P; tri(m-methylphenyl) phosphite; tri-p-tolyl phosphite T=99.84°C; 2: With Lewis acid T=109.84°C; Product distribution / selectivity;
参考文献
BASF AKTIENGESELLSCHAFT
Patent: WO2005/73171 A1, 2005 ;
Location in patent: Page/Page column 32-35; sheet 4 ;