1-溴-2,4,5-三甲氧基苯合成路线 （共 31 条）
反应条件
copper(l) iodide in N,N-dimethyl acetamide; toluene T=152 - 153°C; Yield given. Yields of byproduct given;
参考文献
Huenig, Siegfried; Bau, Robert; Kemmer, Martina; Meixner, Hubert; Metzenthin, Tobias; et al.
European Journal of Organic Chemistry, 1998 , # 2 p. 335 - 348
参考文献
Davidge et al.
Journal of the Chemical Society, 1958 , p. 4569,4573
反应条件
1: 82 percent / LDA / tetrahydrofuran / 4 h / -78 °C 2: 70percent aq. perchloric acid / tetrahydrofuran / 1.25 h 3: 80 percent / pyridinium bromide perbromide / tetrahydrofuran / 1 h / 0 deg C to rt View Scheme
参考文献
Clive, Derrick L. J.; Khodabocus, Ahmad; Vernon, Peter G.; Angoh, A. Gaetan; Bordeleau, Luc; et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1991 , # 6 p. 1433 - 1444
反应条件
1: 68 percent / Cu2O; K2CO3 / 29 h / 190 - 200 °C 2: 1 percent / aq. KOH / ethanol / 4.75 h View Scheme
参考文献
Raposo, M. Manuela M.; Pereira, Alexandra M. B.; Oliveira-Campos, Ana M. F.; Shannon, Patrick V. R.
Journal of Chemical Research, Miniprint, 2000 , # 4 p. 528 - 558
反应条件
poly(4-vinylpyridine)-supported bromate; potassium bromide in acetonitrile
5 h;
参考文献
Tajik, Hassan; Mohammadpoor-Baltork, Iraj; Albadi, Jalal
Synthetic Communications, 2007 , vol. 37, # 2 p. 323 - 328
反应条件
silver carbonate; copper(ll) bromide; palladium dichloride in tetrahydrofuran
T=110°C; 24 h;
参考文献
Peng, Xuefeng; Shao, Xiang-Feng; Liu, Zhong-Quan
Tetrahedron Letters, 2013 , vol. 54, # 24 p. 3079 - 3081
参考文献
Szeki
Chemische Berichte, 1911 , vol. 44, p. 1479
Full Text Show Details
Fabinyi; Szeki
Chemische Berichte, 1910 , vol. 43, p. 2681
反应条件
tetrachloromethane; bromine
参考文献
Meerwein; Hofmann; Schill
Journal fuer Praktische Chemie (Leipzig), 1940 , vol. <2> 154, p. 266,281
反应条件
1: bromine
2: K2CO3; acetone
View Scheme
参考文献
Ballio
Gazzetta Chimica Italiana, 1951 , vol. 81, p. 782,783
反应条件
1: acetic acid
2: methanol. NaOH
3: K2CO3; acetone
View Scheme
参考文献
Ballio
Gazzetta Chimica Italiana, 1951 , vol. 81, p. 782,783
