1 -邻甲苯-1H -吡唑合成路线 (共 9 条)
反应条件
caesium carbonate; copper(I) oxide in N,N-dimethyl-formamide
T=110°C; 18 h;
参考文献
Correa, Arkaitz; Bolm, Carsten
Advanced Synthesis and Catalysis, 2007 , vol. 349, # 17-18 p. 2673 - 2676
反应条件
caesium carbonate; copper(I) oxide in acetonitrile
T=82°C; 70 h;
参考文献
Cellier, Pascal Philippe; Cristau, Henri-Jean; Spindler, Jean-Francis; Taillefer, Marc
Patent: US2003/236413 A1, 2003 ;
Location in patent: Page 21 ;
反应条件
copper diacetate; air; p-benozquinone; palladium diacetate in dichloromethane
T=100°C; 24 h;
参考文献
Chen, Xiao; Goodhue, Charles E.; Yu, Jin-Quan
Journal of the American Chemical Society, 2006 , vol. 128, # 39 p. 12634 - 12635
反应条件
caesium carbonate in N,N-dimethyl-formamide
T=20°C; 0.5 h;
参考文献
Mita, Tsuyoshi; Tanaka, Hiroyuki; Michigami, Kenichi; Sato, Yoshihiro
Synlett, 2014 , vol. 25, # 9 p. 1291 - 1294
反应条件
1: carbon dioxide; 1-phenyl-1H-pyrazole; AlMe2(OMe) With [(η2-cyclooctene)4Rh2(μ-Cl)2]; tri-cyclo-hexyl-phosphine in methanol; N,N-dimethyl acetamide
T=70°C; P=760.051 Torr; 8 h; Inert atmosphere;
2: diazomethyl-trimethyl-silane in methanol; diethyl ether
T=0°C; 1 h; Inert atmosphere; regioselective reaction;
参考文献
Mizuno, Hajime; Takaya, Jun; Iwasawa, Nobuharu
Journal of the American Chemical Society, 2011 , vol. 133, # 5 p. 1251 - 1253
反应条件
Cu-exchanged fluoroapatite; air in methanol
T=20°C; 22 h;
参考文献
Kantam, Mannepalli Lakshmi; Venkanna, Gopaladasu Tirupati; Kumar, Kota Balaji Shiva; Subrahmanyam, Vura Bala
Helvetica Chimica Acta, 2010 , vol. 93, # 5 p. 974 - 979
反应条件
[(η2-cyclooctene)4Rh2(μ-Cl)2]; tri-cyclo-hexyl-phosphine in methanol; N,N-dimethyl acetamide
T=70°C; P=760.051 Torr; 8 h; Inert atmosphere; regioselective reaction;
参考文献
Mizuno, Hajime; Takaya, Jun; Iwasawa, Nobuharu
Journal of the American Chemical Society, 2011 , vol. 133, # 5 p. 1251 - 1253
反应条件
copper
Ullmann Condensation;
参考文献
Mita, Tsuyoshi; Tanaka, Hiroyuki; Michigami, Kenichi; Sato, Yoshihiro
Synlett, 2014 , vol. 25, # 9 p. 1291 - 1294
反应条件
benzene
Erhitzen des Rueckstands auf 140-150grad;
参考文献
Balbiano
Gazzetta Chimica Italiana, 1888 , vol. 18, p. 358
Gazzetta Chimica Italiana, 1889 , vol. 19, p. 689