2,2'-二甲基-5,5'-二羟基-6,6'-联[1,4-萘醌]合成路线 （共 11 条）
反应条件
1: 8 percent / O2 / SnCl4 / CH2Cl2 / 5 h / 23 °C
2: 64 percent / AlI3 / benzene / 4 h / 20 °C
View Scheme
参考文献
Takeya, Tetsuya; Doi, Hirohisa; Ogata, Tokutaro; Okamoto, Iwao; Kotani, Eiichi
Tetrahedron, 2004 , vol. 60, # 41 p. 9049 - 9060
反应条件
2: 88 percent / bis(trimethylsilyl)cyclohexadiene, iodine / CHCl3 / 0.08 h / Ambient temperature
4: 85 percent / sodium acetate, H2 / Pd/C / methanol; benzene / 40 °C
5: 67 percent / 10 percent ammonium cer(IV) nitrate (aq.) / acetonitrile
6: 84 percent / conc. H2SO4
View Scheme
参考文献
Laatsch, Hartmut
Liebigs Annalen der Chemie, 1984 , # 2 p. 319 - 339
反应条件
2: 88 percent / bis(trimethylsilyl)cyclohexadiene, iodine / CHCl3 / 0.08 h / Ambient temperature
4: 85 percent / sodium acetate, H2 / Pd/C / methanol; benzene / 40 °C
5: 67 percent / 10 percent ammonium cer(IV) nitrate (aq.) / acetonitrile
6: 84 percent / conc. H2SO4
View Scheme
参考文献
Laatsch, Hartmut
Liebigs Annalen der Chemie, 1984 , # 2 p. 319 - 339
反应条件
1: 88 percent / bis(trimethylsilyl)cyclohexadiene, iodine / CHCl3 / 0.08 h / Ambient temperature
3: 85 percent / sodium acetate, H2 / Pd/C / methanol; benzene / 40 °C
4: 67 percent / 10 percent ammonium cer(IV) nitrate (aq.) / acetonitrile
5: 84 percent / conc. H2SO4
View Scheme
参考文献
Laatsch, Hartmut
Liebigs Annalen der Chemie, 1984 , # 2 p. 319 - 339
反应条件
1: 85 percent / sodium acetate, H2 / Pd/C / methanol; benzene / 40 °C
2: 67 percent / 10 percent ammonium cer(IV) nitrate (aq.) / acetonitrile
3: 84 percent / conc. H2SO4
View Scheme
参考文献
Laatsch, Hartmut
Liebigs Annalen der Chemie, 1984 , # 2 p. 319 - 339
反应条件
2: 85 percent / sodium acetate, H2 / Pd/C / methanol; benzene / 40 °C
3: 67 percent / 10 percent ammonium cer(IV) nitrate (aq.) / acetonitrile
4: 84 percent / conc. H2SO4
View Scheme
参考文献
Laatsch, Hartmut
Liebigs Annalen der Chemie, 1984 , # 2 p. 319 - 339
参考文献
Laatsch, Hartmut
Liebigs Annalen der Chemie, 1984 , # 2 p. 319 - 339
反应条件
1: 3 percent / Et3N, Ag2O / CH2Cl2
View Scheme
参考文献
Laatsch, Hartmut
Liebigs Annalen der Chemie, 1985 , # 12 p. 2420 - 2442
反应条件
1: 67 percent / 10 percent ammonium cer(IV) nitrate (aq.) / acetonitrile
2: 84 percent / conc. H2SO4
View Scheme
参考文献
Laatsch, Hartmut
Liebigs Annalen der Chemie, 1984 , # 2 p. 319 - 339
反应条件
Yield given. Multistep reaction;
参考文献
Laatsch, Hartmut
Liebigs Annalen der Chemie, 1985 , # 12 p. 2420 - 2442
