Aceanthrylene合成路线 （共 16 条）
反应条件
1: 60 percent / TsOH / diethyl ether / 0.17 h / Heating
2: 0.005 g / DDQ / benzene / 0.5 h / Heating
View Scheme
参考文献
Chung, Ying-Sheng; Kruk, Henry; Barizo, Ophelia M.; Katz, Morris; Lee-Ruff, Edward
Journal of Organic Chemistry, 1987 , vol. 52, # 7 p. 1284 - 1288
反应条件
1: 1.07 g / LAH / diethyl ether / 2 h
2: 60 percent / TsOH / diethyl ether / 0.17 h / Heating
3: 0.005 g / DDQ / benzene / 0.5 h / Heating
View Scheme
参考文献
Chung, Ying-Sheng; Kruk, Henry; Barizo, Ophelia M.; Katz, Morris; Lee-Ruff, Edward
Journal of Organic Chemistry, 1987 , vol. 52, # 7 p. 1284 - 1288
反应条件
1: 1.2 g / HF / 1.) -76 deg C, 30 min, 2.) 0 deg C, overnight
2: 1.07 g / LAH / diethyl ether / 2 h
3: 60 percent / TsOH / diethyl ether / 0.17 h / Heating
4: 0.005 g / DDQ / benzene / 0.5 h / Heating
View Scheme
参考文献
Chung, Ying-Sheng; Kruk, Henry; Barizo, Ophelia M.; Katz, Morris; Lee-Ruff, Edward
Journal of Organic Chemistry, 1987 , vol. 52, # 7 p. 1284 - 1288
反应条件
silica gel
T=1120°C; P=0.03 Torr; Mechanism;
参考文献
Brown; Eastwood; Wong
Tetrahedron Letters, 1993 , vol. 34, # 22 p. 3607 - 3608
反应条件
1.) 960 deg C, 0.02 mm, 2.) 180-200 deg C, 1.25 h; Yields of byproduct given;
参考文献
Anderson, Mark R.; Brown, Roger F. C.; Coulston, Karen J.; Eastwood, Frank W.; Ward, Annemarie
Australian Journal of Chemistry, 1990 , vol. 43, # 7 p. 1137 - 1150
反应条件
T=1100°C; 0.000555556 h; Product distributionMechanism;
参考文献
Scott, Lawrence T.; Roelofs, Nicolas H.
Journal of the American Chemical Society, 1987 , vol. 109, # 18 p. 5461 - 5465
