1,3,3-三甲基-2,3-二氢-1H-吲哚-2-酮合成路线 （共 67 条）
反应条件
1.1: 1,2-diamino-benzene; copper(I) oxide; sodium t-butanolate / tert-butyl alcohol / 4 h / 100 °C / |Sealed tube
2.1: sodium hydride / hexane; tetrahydrofuran / 1 h / 20 °C / |Schlenk technique
2.2: 70 °C / |Schlenk technique
3.1: 1,2-diamino-benzene; copper(I) oxide; sodium t-butanolate / tert-butyl alcohol / 48 h / 100 °C / |Sealed tube
View Scheme
参考文献
Jhan, Yu-Huei; Kang, Ting-Wei; Hsieh, Jen-Chieh
Tetrahedron Letters, 2013 , vol. 54, # 9 p. 1155 - 1159
反应条件
1.1: sodium hydroxide; tert-butyl alcohol / 13 h / 100 °C / |Sealed tube
2.1: sodium hydride / hexane; tetrahydrofuran / 1 h / 20 °C / |Schlenk technique
2.2: 70 °C / |Schlenk technique
3.1: 1,2-diamino-benzene; copper(I) oxide; sodium t-butanolate / tert-butyl alcohol / 48 h / 100 °C / |Sealed tube
View Scheme
参考文献
Jhan, Yu-Huei; Kang, Ting-Wei; Hsieh, Jen-Chieh
Tetrahedron Letters, 2013 , vol. 54, # 9 p. 1155 - 1159
反应条件
Catalyst M-Chromium oxide; sulfuric acid
参考文献
Ciamician; Piccinini
Chemische Berichte, 1896 , vol. 29, p. 2469
Gazzetta Chimica Italiana, 1897 , vol. 27 I, p. 341
反应条件
potassium permanganate
参考文献
Piccinini
Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti, 1898 , vol. <5> 7 I, p. 359
Gazzetta Chimica Italiana, 1898 , vol. 28 II, p. 61
反应条件
sodium hydroxide; trichlorophosphate
1. dioxane, 80 degC, 4h; Yield given. Yields of byproduct given;
参考文献
Prizhiyalgovskaya, N. M.; Kon'kov, L. I.; Tarshits, D. L.; Salmina, S. V.; Segizova, N. T.; Suvorov, N. N.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1987 , vol. 23, # 7 p. 751 - 754
Khimiya Geterotsiklicheskikh Soedinenii, 1987 , # 7 p. 915 - 918
反应条件
sodium hydroxide; trichlorophosphate
1. dioxane, 80 degC, 4h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Prizhiyalgovskaya, N. M.; Kon'kov, L. I.; Tarshits, D. L.; Salmina, S. V.; Segizova, N. T.; Suvorov, N. N.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1987 , vol. 23, # 7 p. 751 - 754
Khimiya Geterotsiklicheskikh Soedinenii, 1987 , # 7 p. 915 - 918
反应条件
sodium hydroxide; trichlorophosphate
1. dioxane, 80 degC, 4h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Prizhiyalgovskaya, N. M.; Kon'kov, L. I.; Tarshits, D. L.; Salmina, S. V.; Segizova, N. T.; Suvorov, N. N.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1987 , vol. 23, # 7 p. 751 - 754
Khimiya Geterotsiklicheskikh Soedinenii, 1987 , # 7 p. 915 - 918
反应条件
sodium hydroxide; trichlorophosphate
1. dioxane, 80 degC, 4h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Prizhiyalgovskaya, N. M.; Kon'kov, L. I.; Tarshits, D. L.; Salmina, S. V.; Segizova, N. T.; Suvorov, N. N.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1987 , vol. 23, # 7 p. 751 - 754
Khimiya Geterotsiklicheskikh Soedinenii, 1987 , # 7 p. 915 - 918
反应条件
sodium hydroxide; trichlorophosphate
1. dioxane, 80 degC, 4h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Prizhiyalgovskaya, N. M.; Kon'kov, L. I.; Tarshits, D. L.; Salmina, S. V.; Segizova, N. T.; Suvorov, N. N.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1987 , vol. 23, # 7 p. 751 - 754
Khimiya Geterotsiklicheskikh Soedinenii, 1987 , # 7 p. 915 - 918
反应条件
sodium hydroxide; trichlorophosphate
1. dioxane, 80 degC, 4h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Prizhiyalgovskaya, N. M.; Kon'kov, L. I.; Tarshits, D. L.; Salmina, S. V.; Segizova, N. T.; Suvorov, N. N.
Chemistry of Heterocyclic Compounds (New York, NY, United States), 1987 , vol. 23, # 7 p. 751 - 754
Khimiya Geterotsiklicheskikh Soedinenii, 1987 , # 7 p. 915 - 918
