3-甲氧基-1,7-辛二烯合成路线 （共 22 条）
反应条件
bis(acetylacetonate)nickel(II); sodium tetrahydroborate; C35H34N2P2 in tetrahydrofuran
T=-20 - 80°C; 17 h; Schlenk techniqueCooling with acetone-dry ice;
参考文献
Bigot, Sandra; El Alami, Mohammed Samir Ibn; Mifleur, Alexis; Castanet, Yves; Suisse, Isabelle; Mortreux, Andre; Sauthier, Mathieu
Chemistry - A European Journal, 2013 , vol. 19, # 30 p. 9785 - 9788
反应条件
(diallyl ether)(triphenylphosphane)palladium(0)
T=-10°C; Dimerization; telomerization, Diels-Alder reaction; 6 h; Product distribution; Further Variations:CatalystsTemperaturesreaction time, diene to metanol ratio, catalyst conc.;
参考文献
Vollmueller, Frank; Krause, Jochen; Klein, Susanne; Maegerlein, Wolfgang; Beller, Matthias
European Journal of Inorganic Chemistry, 2000 , # 8 p. 1825 - 1832
反应条件
(Pd-hmpa,dba(1+)*PF6(1-)
T=80°C; 20 h; different Pd-catalysts, other alcohols as educts, different time and ratio of butadiene; Product distribution;
参考文献
Grenouillet, Pierre; Neibecker, Denis; Poirier, Jacques; Tkatchenko, Igor
Angewandte Chemie, 1982 , vol. 94, # 10 p. 796 - 797
反应条件
Pd(P(C6H4C6H3(OCH3)2)(C6H11)2)(CH2CHSi(CH3)2OSi(CH3)2CHCH2); sodium methylate
T=60°C; 16 h; Autoclave; chemoselective reaction;
参考文献
Tschan, Mathieu J.-L.; Garcia-Suarez, Eduardo J.; Freixa, Zoraida; Launay, Helene; Hagen, Henk; Benet-Buchholz, Jordi; Van Leeuwen, Piet W.N.M.
Journal of the American Chemical Society, 2010 , vol. 132, # 18 p. 6463 - 6473
反应条件
1: With tert-butylisonitrile; palladium(II) 2,4-pentanedionate
T=100°C; 3 h;
2: With water; diethylphosphinoethane in methanol
T=100°C; 3 h; Product distribution / selectivity;
参考文献
KURARAY CO., LTD.
Patent: WO2005/121059 A1, 2005 ;
Location in patent: Page/Page column 13-14 ;
反应条件
1: With tert-butylisonitrile; palladium(II) 2,4-pentanedionate
T=100°C; 3 h;
2: With water; diethylphosphinoethane in methanol
T=100°C; 3 h; Product distribution / selectivity;
参考文献
KURARAY CO., LTD.
Patent: WO2005/121059 A1, 2005 ;
Location in patent: Page/Page column 15 ;
反应条件
phosphinated polystyrene-bound Pd(0) in benzene
T=80°C; 5 h; also without the solvent, different times; various alcohols and phenol; Product distribution;
参考文献
Kaneda, Kiyotomi; Kurosaki, Hiroo; Terasawa, Masami; Imanaka, Toshinobu; Teranishi, Shiichiro
Journal of Organic Chemistry, 1981 , vol. 46, # 11 p. 2356 - 2362
反应条件
palladium diacetate; triphenylphosphine; 1-n-butyl-2,3-dimethylimidazolium tetrafluoroborate
T=85°C; 1 h;
参考文献
CENTRE NATIONAL DE,
Patent: EP1201657 A1, 2002 ;
Location in patent: Example 1 ;
反应条件
palladium diacetate; triphenylphosphine; 1-n-butyl-2,3-dimethylimidazolium bistrifluoromethylsulfonylamide in n-heptane
T=85°C; 3 h;
参考文献
CENTRE NATIONAL DE,
Patent: EP1201657 A1, 2002 ;
Location in patent: Example 6 ;
反应条件
palladium diacetate; triphenylphosphine; 1-ethyl-3-methylimidazolium bistrifluoromethylsulfonylamide
T=85°C; 22 h;
参考文献
CENTRE NATIONAL DE,
Patent: EP1201657 A1, 2002 ;
Location in patent: Example 7 ;
