1-fluoro-2,4,6-trimethylpyridinium hexafluorophosphate; C10H18CuN2(1+)*CF3O3S(1-); silver fluoride in tetrahydrofuran T=80°C; 18 h; Inert atmosphere;

1: bis(η4-1,5-cyclooctadiene)-di-μ-methoxy-diiridium(I) / tetrahydrofuran / 18 h / 80 °C / |Inert atmosphere 2: silver fluoride; C10H18CuN2(1+)*CF3O3S(1-); 1-fluoro-2,4,6-trimethylpyridinium hexafluorophosphate / tetrahydrofuran / 18 h / 80 °C / |Inert atmosphere View Scheme

1: With boron tribromide in dichloromethane T=-70 - 20°C; 0.25 h; 2: With water; sodium hydrogencarbonate in dichloromethane T=20°C; pH=~ 6;

[Pd(η3-1-Ph-allyl)(μ-Cl)]2; (Mor-DalPhos); ammonia; sodium t-butanolate in 1,4-dioxane T=50°C; 16 h; Inert atmosphere; chemoselective reaction;