ammonia; sodium in tetrahydrofuran 2 h; Heatingdifferent NH3/THF/substrate ratios; also with addition of methanol as quenching agent; also with addition of 2-methyl-2-propanol; Product distribution;
参考文献
Journal of Organic Chemistry, , vol. 58, # 19 p. 5063 - 5066
T=24.9°C; P=760 Torr; ΔH0, ΔS0; thermodynamic parameters of dehydration reaction of normal paraffins to olefins; entalpy end entropy differences for the formation of monoolefins from normal paraffins; Thermodynamic data;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 36, # 4 p. 674 - 677
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 4 p. 745 - 748
n-butyllithium; hexane multistep reaction: 1.) THF, 0 deg C, then room t., 2 h, 2.) THF, -78 deg C to room t., 30 min; reactions under var. conditions and var. with reagents; Product distribution;
