(+)-柠檬烯 1,2-环氧合成路线 (共 24 条)
反应条件
dihydrogen peroxide in acetonitrile T=80°C; P=760.051 Torr; 24 h; Reagent/catalyst;
参考文献
Balula, Salete S.; Santos, Isabel C.M.S.; Cunha-Silva, Luis; Carvalho, Ana P.; Pires, Joao; Freire, Cristina; Cavaleiro, Jose A.S.; De Castro, Baltazar; Cavaleiro, Ana M.V.
Catalysis Today, 2013 , vol. 203, p. 95 - 102
反应条件
urea hydrogen peroxide addition compound; methyltrioxorhenium (VII) in dichloromethane T=20°C; 0.5 h;
参考文献
Boehlow, Todd R.; Spilling, Christopher D.
Tetrahedron Letters, 1996 , vol. 37, # 16 p. 2717 - 2720
反应条件
urea hydrogen peroxide addition compound; methyltrioxorhenium (VII) in dichloromethane T=20°C; 0.25 h; 3 equiv. urea-H2O2 adduct; Yield given. Yields of byproduct given;
参考文献
Tetrahedron Letters, , vol. 37, # 16 p. 2717 - 2720
反应条件
tert.-butylhydroperoxide; [Mo2(O)4{[2,2'-(1,3-phenylene)bis(4,5-dihydrooxazole-4,2-diyl)]dimethanol}(acac)2] in 1,2-dichloro-ethane 6 h; Reflux; regioselective reaction;
参考文献
Polyhedron, , vol. 72, p. 19 - 26
反应条件
air; benzaldehyde; molecular sieve T=49.85°C; P=22501.8 Torr; 8 h; Yield givenYields of byproduct given. Title compound not separated from byproducts;
参考文献
Chemical Communications, , # 9 p. 829 - 830
反应条件
tert.-butylhydroperoxide; C22H38ClMoNO5Si T=55°C; P=760.051 Torr; 24 h; Product distribution; Further Variations:CatalystsSolvents;
参考文献
New Journal of Chemistry, , vol. 25, # 7 p. 959 - 963
反应条件
dihydrogen peroxide; Amberlite IRA 900; PW4O24[(C4H9)4N]3 in acetonitrile T=38°C; Epoxidation; 24 h;
参考文献
Journal of Organic Chemistry, , vol. 64, # 19 p. 7267 - 7270
反应条件
tellurium; diethyl sodium phosphite in ethanol 18.5 h; Ambient temperature;
参考文献
Clive, Derrick L. J.; Menchen, Steven M.
Journal of Organic Chemistry, 1980 , vol. 45, # 12 p. 2347 - 2354
反应条件
tert.-butylhydroperoxide; tetrabutylammomium bromide; copper dichloride in dichloromethane; water T=25°C; 14 h; Yield given. Yields of byproduct given;
参考文献
Journal of the Chemical Society. Perkin Transactions 2, , # 11 p. 2429 - 2434
反应条件
3-chloro-benzenecarboperoxoic acid in acetonitrile T=20°C; 4 h; Overall yield = 75 percent;
参考文献
Journal of the Brazilian Chemical Society, , vol. 23, # 8 p. 1411 - 1420