(+)-柠檬烯 1,2-环氧合成路线 （共 24 条）
反应条件
2: 53 percent / CHCl3 / 0.5 h / Heating View Scheme
参考文献
Wilkinson, Shane M.; Price, Jason; Kassiou, Michael
Tetrahedron Letters, 2013 , vol. 54, # 1 p. 52 - 54
反应条件
1: With sodium tetrahydroborate; diphenyl diselenide in ethanol
2 h; Heating;
2: With dihydrogen peroxide in tetrahydrofuran
2 h; Heating;
参考文献
PRESIDENT AND FELLOWS OF HARVARD COLLEGE; RITTER, Tobias; FURUYA, Takeru; TANG, Pingping
Patent: WO2010/59943 A2, 2010 ;
Location in patent: Page/Page column 69;70 ;
反应条件
1.1: lithium diisopropyl amide / tetrahydrofuran / -78 °C
2.1: pyridine / dichloromethane / 0 - 20 °C
3.1: tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran / 15 h / 110 °C / |Inert atmosphere; |Sealed tube
3.2: 20 °C
View Scheme
参考文献
Geoghegan, Kimberly; Evans, Paul
Tetrahedron Letters, 2014 , vol. 55, # 8 p. 1431 - 1433
反应条件
sulfur dioxide; epoxysulfonyl fluoride in carbon disulfide
Yield given. Yields of byproduct given;
参考文献
Baig, Mirza Azam; Banthorpe, Derek V.; Carr, Graham; Whittaker, David
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1989 , p. 1981 - 1986
