1,10-phenanthroline; copper(II) bis(trifluoromethanesulfonate); sodium hydrogencarbonate; potassium hexacyanoferrate(III) in 1,2-dichloro-benzene T=130°C; 24 h; Sealed tube;

1,10-phenanthroline; (NH4)2CO3; copper(II) bis(trifluoromethanesulfonate); sodium hydrogencarbonate; potassium hexacyanoferrate(III) in 1,2-dichloro-benzene T=130°C; 24 h; Sealed tube;

1: acetyl chloride / 24 h / 0 - 20 °C 2: sodium hydrogencarbonate; potassium hexacyanoferrate(III); 1,10-phenanthroline; copper(II) bis(trifluoromethanesulfonate); (NH4)2CO3 / 1,2-dichloro-benzene / 24 h / 130 °C / |Sealed tube View Scheme

T=218°C;

1: PCl5 / 135 °C 2: concentrated alcoholic ammonia / 150 °C View Scheme

1: diluted KOH-solution; hydrazine sulfate 2: PCl5 / 135 °C 3: concentrated alcoholic ammonia / 150 °C View Scheme