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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
4-溴苯乙烯
合成路线
（共 224 条）
2039-82-9
4-溴苯乙烯
+
122-39-4
二苯胺
→
反应条件
25069-74-3
N,N-二苯基-4-乙烯基苯胺
反应条件
palladium diacetate; tri-tert-butyl phosphine; sodium t-butanolate in toluene T=100°C; 1 h;
参考文献
Lindner, Stefan M.; Thelakkat, Mukundan
Macromolecules, 2004 , vol. 37, # 24 p. 8832 - 8835
2039-82-9
4-溴苯乙烯
→
反应条件
2351-50-0
1-碘-4-乙烯基苯
反应条件
1: With n-butyllithium in tetrahydrofuran T=-78 - 20°C; Inert atmosphere; 2: With iodine in tetrahydrofuran T=-78 - 20°C;
参考文献
Tyson, Elizabeth L.; Ament, Michael S.; Yoon, Tehshik P.
Journal of Organic Chemistry, 2013 , vol. 78, # 5 p. 2046 - 2050
2039-82-9
4-溴苯乙烯
→
反应条件
148684-05-3
(S)-4-溴苯乙烯氧化物
反应条件
titanium(IV) isopropylate; C50H46N2O4; dihydrogen peroxide in dichloromethane; water T=20°C; 9 h; optical yield given as percent eeenantioselective reaction;
参考文献
Xiong, Donglu; Wu, Mei; Wang, Shoufeng; Li, Fuwei; Xia, Chungu; Sun, Wei
Tetrahedron Asymmetry, 2010 , vol. 21, # 3 p. 374 - 378
2039-82-9
4-溴苯乙烯
→
反应条件
62566-68-1
(R)-4-溴氧化苯乙烯
+
148684-05-3
(S)-4-溴苯乙烯氧化物
反应条件
iodosylbenzene; homochiral chloroiron(III) porphyrin in benzene T=25°C; 3 h; other reagents, solvents, temperatures, reaction times; Product distribution;
参考文献
Hollmann, Frank; Lin, Po-Chi; Witholt, Bernard; Schmid, Andreas
Journal of the American Chemical Society, 2003 , vol. 125, # 27 p. 8209 - 8217
2039-82-9
4-溴苯乙烯
→
反应条件
7099-87-8
2-(4-溴苯基)-2-氧代乙酸
反应条件
1: With potassium permanganate; sodium hydroxide in water T=50°C; 0.333333 h; 2: With hydrogenchloride in water
参考文献
Jin, Zhe; Yang, Liu; Liu, Si-Jie; Wang, Jian; Li, Shuo; Lin, Huang-Quan; Wan, David Chi Cheong; Hu, Chun
Archives of Pharmacal Research, 2010 , vol. 33, # 10 p. 1641 - 1649
2039-82-9
4-溴苯乙烯
→
反应条件
71559-14-3
反应条件
sodium azide; cis-1,4-bis(triphenylphosphonium)-2-butene peroxodisulfate; oxygen in methanol T=0°C; 1.08333 h;
参考文献
Badri, Rashid; Gorjizadeh, Maryam
Synthetic Communications, 2012 , vol. 42, # 14 p. 2058 - 2066
2039-82-9
4-溴苯乙烯
→
反应条件
59862-55-4
反应条件
sodium tetrahydroborate; tert.-butylnitrite; Fe pythalocyanine; hydrogen in ethanol T=20°C; P=7500.75 Torr; 3 h;
参考文献
Prateeptongkum, Saisuree; Jovel, Irina; Jackstell, Ralf; Vogl, Nadine; Weckbecker, Christoph; Beller, Matthias
Chemical Communications, 2009 , # 15 p. 1990 - 1992
2039-82-9
4-溴苯乙烯
→
反应条件
1372804-72-2
+
7474-19-3
反应条件
1: toluene / 20 °C 2: trifluorormethanesulfonic acid / 0.5 h / Reflux View Scheme
参考文献
King, Frank D.; Caddick, Stephen
Organic and Biomolecular Chemistry, 2012 , vol. 10, # 16 p. 3244 - 3252
2039-82-9
4-溴苯乙烯
→
反应条件
77785-94-5
4-烯丙基苯甲醛
反应条件
1: cesium fluoride; bis(dibenzylideneacetone)-palladium(0); tri-cyclo-hexyl-phosphine / 1,4-dioxane / 48 h / Inert atmosphere; Reflux 2: oxygen / dimethyl sulfoxide / 24 h / 20 °C / 1500.15 Torr / pH 6 / aq. buffer; Enzymatic reaction View Scheme
参考文献
Paul, Caroline E.; Rajagopalan, Aashrita; Lavandera, Ivan; Gotor-Fernandez, Vicente; Kroutil, Wolfgang; Gotor, Vicente
Chemical Communications, 2012 , vol. 48, # 27 p. 3303 - 3305
2039-82-9
4-溴苯乙烯
→
反应条件
81585-72-0
反应条件
iodine; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione in dimethyl sulfoxide T=20°C; 0.5 h;
参考文献
Zhu, Yan-Ping; Jia, Feng-Cheng; Liu, Mei-Cai; Wu, An-Xin
Organic Letters, 2012 , vol. 14, # 17 p. 4414 - 4417
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