9,9-二己基芴-2,7-二硼酸合成路线 （共 8 条）
反应条件
1: With magnesium in tetrahydrofuran Metallation; 2: With boric acid trimethyl ester in tetrahydrofuran T=-78 - 20°C; Substitution; 50 h; 3: With sulfuric acid; water Hydrolysis;
参考文献
Yu, Wang-Lin; Pei, Jian; Cao, Yong; Huang, Wei; Heeger, Alan J.
Chemical Communications, 1999 , # 18 p. 1837 - 1838
反应条件
iodine; magnesium in tetrahydrofuran; hexane; acetone
参考文献
National University Of Singapore
Patent: US2007/290199 A1, 2007 ;
反应条件
1: 2,7-dibromo-9,9-di-n-hexylfluorene With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 1 h; Inert atmosphere; 2: tri-isopropoxy-borane With hydrogenchloride in tetrahydrofuran; hexane T=-78 - 20°C;
参考文献
Lin, Tzu-Chau; Li, Mei-Ling; Liu, Che-Yu; Tsai, Ming-Yu; Lee, Ying-Hsuan; Febriani, Yuyun; Lin, Ja-Hon; Shen, Yu-Kai
European Journal of Organic Chemistry, 2014 , vol. 2014, # 8 p. 1615 - 1621
反应条件
1.1: 91 percent / t-BuOK / tetrahydrofuran / 4 h / 20 °C 2.1: BuLi / tetrahydrofuran; hexane / 6 h / -78 °C 2.2: tetrahydrofuran; hexane / 12 h / -78 - 20 °C 3.1: 24.3 g / aq. HCl View Scheme
参考文献
Chemical Communications, , # 27 p. 3397 - 3399
反应条件
1.1: 80 percent / aq. H2SO4; acetic acid; Br2 / KBrO3 / 4 h / 40 - 55 °C 2.1: 91 percent / t-BuOK / tetrahydrofuran / 4 h / 20 °C 3.1: BuLi / tetrahydrofuran; hexane / 6 h / -78 °C 3.2: tetrahydrofuran; hexane / 12 h / -78 - 20 °C 4.1: 24.3 g / aq. HCl View Scheme
参考文献
Chemical Communications, , # 27 p. 3397 - 3399
反应条件
n-butyllithium in tetrahydrofuran Br compd., n-BuLi and B compd. were reacted in THF at -78°C; mixt. was warmed to 20°C; H2O added;
参考文献
Hughes, Gregory; Wang, Changsheng; Batsanov, Andrei S.; Fern, Michael; Frank, Stephen; Bryce, Martin R.; Perepichka, Igor F.; Monkman, Andrew P.; Lyons, Benjamin P.
Organic and Biomolecular Chemistry, 2003 , vol. 1, # 17 p. 3069 - 3077
反应条件
1.1: 96 percent / triethylbenzylammonium chloride; aq. NaOH / dimethylsulfoxide 2.1: Mg; I2 / tetrahydrofuran / Heating 2.2: tetrahydrofuran / -78 °C 3.1: aq. H2SO4 View Scheme
参考文献
Macromolecules, , vol. 36, # 19 p. 6995 - 7003
参考文献
Ling; Kang; Neoh; Huang, Wei
Macromolecules, 2003 , vol. 36, # 19 p. 6995 - 7003
