2,6-di-tert-butyl-4-methylpyridine in 1,2-dichloro-ethane
24 h; Ambient temperaturecycloadditions to further olefins: cyclopentene, cyclohexene, cycloheptene, (E)-cyclooctene, (Z)- and (E)-2-butene; further reagent: AgBF4; MechanismProduct distribution;
参考文献
Harder, Ingo; Hanack, Michael
Chemische Berichte, 1985 , vol. 118, # 7 p. 2974 - 2992
Mentzer; Dat Xuong
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1946 , vol. 222, p. 1004
Bulletin de la Societe Chimique de France, 1947 , p. 885,891
Irradiationin alcohol solvents; ESR studies of the radicals formed by photofragmentation of this and further 2,2-dialkyl-2-alkylaminoacetophenones, further solvent; Product distributionMechanism;
参考文献
Leopold, Detlev; Fischer, Hanns
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1992 , # 4 p. 513 - 518
1-(2-methoxyphenyl)-2-methylpropan-1-one; trimethylaluminum; tri-n-butyl-tin hydride
1.) toluene, from -78 deg C to -40 deg C, 10 min, 2.) toluene; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Ooi; Uraguchi; Kagoshima; Maruoka
Journal of the American Chemical Society, 1998 , vol. 120, # 21 p. 5327 - 5328
