1,2-二(苯基)丙-1-酮合成路线 （共 138 条）
反应条件
anhydrous magnesium perchlorate in dichloromethane
2.5 h; Heatingother Lewis acids; Product distributionMechanism;
参考文献
Bach, Robert D.; Domagala, John M.
Journal of Organic Chemistry, 1984 , vol. 49, # 22 p. 4181 - 4188
反应条件
potassium tert-butylate; iron(II) chloride
1.) DMSO, 5 min, 2.) DMSO, RT, 2 h; Yield given. Multistep reaction;
参考文献
Galli, Carlo; Gentili, Patrizia; Guarnieri, Alessandra
Gazzetta Chimica Italiana, 1997 , vol. 127, # 3 p. 159 - 164
反应条件
1.1: Dess-Martin periodane / dichloromethane / 0.75 h / 20 °C
2.1: benzene / |Irradiation
3.1: potassium tert-butylate / tetrahydrofuran / 0.75 h / 0 °C
3.2: 2 h / 3 - 20 °C
View Scheme
参考文献
Kulasekharan, Revathy; Maddipatla, Murthy V. S. N.; Parthasarathy, Anand; Ramamurthy
Journal of Organic Chemistry, 2013 , vol. 78, # 3 p. 942 - 949
反应条件
1.1: Dess-Martin periodane / dichloromethane / 0.75 h / 20 °C
2.1: benzene / |Irradiation
3.1: potassium tert-butylate / tetrahydrofuran / 0.75 h / 0 °C
3.2: 2 h / 3 - 20 °C
View Scheme
参考文献
Kulasekharan, Revathy; Maddipatla, Murthy V. S. N.; Parthasarathy, Anand; Ramamurthy
Journal of Organic Chemistry, 2013 , vol. 78, # 3 p. 942 - 949
反应条件
1.1: benzene / |Irradiation
2.1: potassium tert-butylate / tetrahydrofuran / 0.75 h / 0 °C
2.2: 2 h / 3 - 20 °C
View Scheme
参考文献
Kulasekharan, Revathy; Maddipatla, Murthy V. S. N.; Parthasarathy, Anand; Ramamurthy
Journal of Organic Chemistry, 2013 , vol. 78, # 3 p. 942 - 949
反应条件
1.1: benzene / |Irradiation
2.1: potassium tert-butylate / tetrahydrofuran / 0.75 h / 0 °C
2.2: 2 h / 3 - 20 °C
View Scheme
参考文献
Kulasekharan, Revathy; Maddipatla, Murthy V. S. N.; Parthasarathy, Anand; Ramamurthy
Journal of Organic Chemistry, 2013 , vol. 78, # 3 p. 942 - 949
反应条件
1.1: RuCl2[(S)-(DM-SEGPHOS)][(S)-DAIPEN]; hydrogen; potassium tert-butylate / isopropyl alcohol / 40 h / 25 °C / 5171.62 Torr / |Glovebox
2.1: Dess-Martin periodane / dichloromethane / 0.75 h / 20 °C
3.1: benzene / |Irradiation
4.1: potassium tert-butylate / tetrahydrofuran / 0.75 h / 0 °C
4.2: 2 h / 3 - 20 °C
View Scheme
参考文献
Kulasekharan, Revathy; Maddipatla, Murthy V. S. N.; Parthasarathy, Anand; Ramamurthy
Journal of Organic Chemistry, 2013 , vol. 78, # 3 p. 942 - 949
反应条件
1.1: RuCl2[(S)-(DM-SEGPHOS)][(S)-DAIPEN]; hydrogen; potassium tert-butylate / isopropyl alcohol / 40 h / 25 °C / 5171.62 Torr / |Glovebox
2.1: Dess-Martin periodane / dichloromethane / 0.75 h / 20 °C
3.1: benzene / |Irradiation
4.1: potassium tert-butylate / tetrahydrofuran / 0.75 h / 0 °C
4.2: 2 h / 3 - 20 °C
View Scheme
参考文献
Kulasekharan, Revathy; Maddipatla, Murthy V. S. N.; Parthasarathy, Anand; Ramamurthy
Journal of Organic Chemistry, 2013 , vol. 78, # 3 p. 942 - 949
反应条件
1: toluene / 24 h / 110 °C / |Schlenk technique; |Inert atmosphere
2: Ni{1,3-bis-(2,6-diisopropylphenyl)imidazol-2-ylidene}Clcyclopentadienyl; sodium t-butanolate / 24 h / 110 °C / |Schlenk technique; |Inert atmosphere
View Scheme
参考文献
Henrion, Mickael; Chetcuti, Michael J.; Ritleng, Vincent
Chemical Communications, 2014 , vol. 50, # 35 p. 4624 - 4627
参考文献
Ashby,E.C.; Willard,G.F.
Journal of Organic Chemistry, 1978 , vol. 43, # 25 p. 4750 - 4758
Full Text View citing articles Show Details
Ashby,E.C. et al.
Journal of Organic Chemistry, 1979 , vol. 44, p. 1221 - 1232
