N in potassium hydroxide; ammonium hydroxide aq. KOH soln. dropped into CuSO4 soln. under rigorous stirring at ambient temp. (ca 19°C) then NH3 soln. dropped, stirred for 3 min then mixed soln. kept static in sealed vessel for 12 h; another route if feeding order of solns. changed; filtered, washed thoroughly with deionized H2O, dried in vac. at 25°C for 12 h; nanowires formed;
参考文献
Journal of Physical Chemistry B, , vol. 108, # 46 p. 17825 - 17831
in water to soln. ligand*4HCl in water soln. Cu(ClO4)2*6H2O in water was added, pH was adjusted to 9 with 1 M NaOH; ppt. was filtered off, soln. was left to slowly evaporate; elem. anal.;
ammonium hydroxide; (NH4)2S2O8 in water NaOH, aq. NH3 and (NH4)2S2O8 mixed in distilled water; copper foil immersed in the soln. at room temp. for 45 min; rinsed with distilled water and absolute EtOH; dried in air;
参考文献
Chemical Physics Letters, , vol. 434, # 4-6 p. 256 - 259
sodium hydroxide in sodium hydroxide equilibration (isomolar components concn. (0.251 M), NaOH>=66.7 mol-percent, (20+/-0.05)°C), pptn.; monitoring by refractive index of liquid phase;
参考文献
Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), , vol. 24, p. 1202 - 1205
Zhurnal Neorganicheskoi Khimii, , vol. 24, p. 2172 - 2175
