1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷合成路线 （共 87 条）
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
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参考文献
3M INNOVATIVE PROPERTIES COMPANY
Patent: WO2003/102003 A1, 2003 ;
Location in patent: Page 7 ;
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
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反应条件
T=120°C; 40 h; Inert atmosphere;
参考文献
Chang, Shih-Huang; Han, Jeng-Liang; Tseng, Susan Y.; Lee, Hsin-Yu; Lin, Chin-Wei; Lin, Yu-Chen; Jeng, Wen-Yih; Wang, Andrew H.-J.; Wu, Chung-Yi; Wong, Chi-Huey
Journal of the American Chemical Society, 2010 , vol. 132, # 38 p. 13371 - 13380
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷
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反应条件
trisodium phosphorothioate in methanol
Substitution; Oxidative dimerization; 72 h; Heating;
参考文献
Naud; Calas; Blancou; Commeyras
Journal of Fluorine Chemistry, 2000 , vol. 104, # 2 p. 173 - 183
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
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反应条件
tri-n-butylhexadecylphosphonium bromide
T=70°C; 6 h;
参考文献
Naud; Calas; Blancou; Commeyras
Phosphorus, Sulfur and Silicon and Related Elements, 2000 , vol. 161, p. 29 - 38
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷
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反应条件
1: NaOMe / methanol / 5 h / 70 °C
2: aq. NaOH / methanol / 3 h / Heating
View Scheme
参考文献
Naud; Calas; Blancou; Commeyras
Journal of Fluorine Chemistry, 2000 , vol. 104, # 2 p. 173 - 183
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647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
water; silver nitrate; copper(II) sulfate
T=180°C; Gas phase; Conversion of starting material;
参考文献
Daikin Industries, Ltd.
Patent: US6664430 B1, 2003 ;
Location in patent: Page column 8-9 ;
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
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反应条件
4-methoxy-phenol; hydroquinone in tert-butyl alcohol
T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
DAIKIN INDUSTRIES, LTD.
Patent: EP1757578 A1, 2007 ;
Location in patent: Page/Page column 6-7; 8-9 ;
