1,1,2,2-四氢全氟己基碘合成路线 （共 24 条）
反应条件
1: K2CO3 / tetrahydrofuran / 24 h / 70 °C
2: KOH / ethanol / 80 °C
3: 3 h / 195 °C
4: LiAlH4 / diethyl ether / 12 h / 40 °C
View Scheme
参考文献
Mureau, Natacha; Guittard, Frederic; Geribaldi, Serge
Tetrahedron Letters, 2000 , vol. 41, # 16 p. 2885 - 2889
反应条件
1: K2CO3 / tetrahydrofuran / 24 h / 70 °C
2: KOH / ethanol / 80 °C
3: 3 h / 195 °C
4: LiAlH4 / diethyl ether / 12 h / 40 °C
5: PBr3 / diethyl ether / 12 h / 40 °C
View Scheme
参考文献
Mureau, Natacha; Guittard, Frederic; Geribaldi, Serge
Tetrahedron Letters, 2000 , vol. 41, # 16 p. 2885 - 2889
反应条件
hydrogenchloride; zinc
up to 70 deg C;
参考文献
Puy, Michael Van Der; Poss, Andrew J.; Persichini, Phillip J.; Ellis, Lois A. S.
Journal of Fluorine Chemistry, 1994 , vol. 67, # 3 p. 215 - 224
→
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
water; silver nitrate; copper(II) sulfate
T=180°C; Gas phase; Conversion of starting material;
参考文献
Daikin Industries, Ltd.
Patent: US6664430 B1, 2003 ;
Location in patent: Page column 8-9 ;
