1-碘-1H,1H,2H,2H-全氟辛烷 合成路线 （共 102 条）
反应条件
1: 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-1-iodooctane With n-butyllithium
2: N,N-dimethyl-formamide
3: With hydrogenchloride
参考文献
Chu, Qianli; O'Neal, Kristi; Osipov, Maksim; Ngwendson, Julius N.; Geib, Steven J.; Weber, Stephen G.; Curran, Dennis P.
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反应条件
857637-92-4 4-苄基-5-(3,3,4,4,5,5,6,6,7,7,8,8,8-十三氟辛基)-1,3-恶唑烷-2-酮
反应条件
1.1: Mg / diethyl ether
1.2: 15 percent / diethyl ether / 4 h
2.1: 97 percent / LiAlH(OtBu)3 / ethanol / -78 - 20 °C
3.1: NaH / tetrahydrofuran
View Scheme
参考文献
Hein, Jason E.; Geary, Laina M.; Jaworski, Ashley A.; Hultin, Philip G.
反应条件
1: 87 percent / sodium hydroxide / 2-methyl-propan-2-ol / 3 h / Heating
2: 97 percent / sodium periodate / H2O; methanol / 6 h / 0 - 20 °C
View Scheme
参考文献
Cirkva, Vladimir; Duchek, Jan; Kaplanek, Robert; Paleta, Oldrich; Michalek, Jiri; Pradny, Martin; Chmelikova, Dana; Wichterlova, Jana
反应条件
in ethanol
T=76 - 80°C; 4 h;
参考文献
Brace, Neal O.
反应条件
1: NaOMe / methanol / 5 h / 70 °C
2: aq. NaOH / methanol / 3 h / Heating
View Scheme
参考文献
Werner, K. von; Blank, H.; Gisser, A.; Manhart, E.
反应条件
trisodium phosphorothioate in methanol
Substitution; Oxidative dimerization; 72 h; Heating;
参考文献
Naud; Calas; Blancou; Commeyras
反应条件
tri-n-butylhexadecylphosphonium bromide
T=70°C; 6 h;
参考文献
Naud; Calas; Blancou; Commeyras
反应条件
triethylamine; bis-triphenylphosphine-palladium(II) chloride
T=100°C; P=22800 Torr; 12 h;
参考文献
Urata, Hisao; Kosukegawa, Osamu; Ishii, Yoshimitsu; Yugary, Hideki; Fuchikami, Takamasa
反应条件
sodium azide; methyl-tridecylammonium chloride
T=90 - 100°C;
参考文献
Palomo, Claudio; Aizpurua, Jesus M.; Loinaz, Iraida; Fernandez-Berridi, Maria Jose; Irusta, Lourdes
反应条件
1: K2CO3 / tetrahydrofuran / 24 h / 70 °C
2: KOH / ethanol / 80 °C
3: 3 h / 195 °C
4: LiAlH4 / diethyl ether / 12 h / 40 °C
View Scheme
参考文献
Mureau, Natacha; Guittard, Frederic; Geribaldi, Serge
