1-碘-1H,1H,2H,2H-全氟辛烷合成路线 （共 102 条）
→
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
in toluene 5.5 h; Heating; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Brace
Journal of Organic Chemistry, 1995 , vol. 60, # 7 p. 2059 - 2071
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
→
反应条件
4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
DAIKIN INDUSTRIES, LTD.
Patent: EP1757578 A1, 2007 ;
Location in patent: Page/Page column 6-7; 8-9 ;
→
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
water T=140°C; 8 h; other temperatures, duration, the effect of mole ratios; Rate constantProduct distributionMechanism;
参考文献
Journal of Organic Chemistry, , vol. 61, # 19 p. 6504 - 6516
→
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
water T=140°C; 1 h; var. temp., time, substrate (DMF, 1,2-ethanyl-bis-formamide) investigated; Product distributionRate constant;
参考文献
Brace, Neal O.
Journal of Fluorine Chemistry, 1986 , vol. 31, p. 151 - 174
→
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
T=140°C; 1 h; other times; also with ε-caprolactam; Rate constantMechanism;
参考文献
Brace
Journal of Organic Chemistry, 1995 , vol. 60, # 7 p. 2059 - 2071
→
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
T=140°C; 1 h; var. temp., time, substrate (DMF) investigated; Product distributionRate constant;
参考文献
Brace, Neal O.
Journal of Fluorine Chemistry, 1986 , vol. 31, p. 151 - 174
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
→
反应条件
4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
DAIKIN INDUSTRIES, LTD.
Patent: EP1757578 A1, 2007 ;
Location in patent: Page/Page column 6-7; 8-9 ;
→
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
water; silver nitrate; copper(II) sulfate T=180°C; Gas phase; Conversion of starting material;
参考文献
Daikin Industries, Ltd.
Patent: US6664430 B1, 2003 ;
Location in patent: Page column 8-9 ;
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
→
反应条件
4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
DAIKIN INDUSTRIES, LTD.
Patent: EP1757578 A1, 2007 ;
Location in patent: Page/Page column 6-7; 8-9 ;
反应条件
magnesium in diethyl ether
参考文献
Thebault, Pascal; Taffin de Givenchy, Elisabeth; Starita-Geribaldi, Mireille; Guittard, Frederic; Geribaldi, Serge
Journal of Fluorine Chemistry, 2007 , vol. 128, # 3 p. 211 - 218
