1-碘-1H,1H,2H,2H-全氟辛烷合成路线 （共 102 条）
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647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
in N,N-dimethyl-formamide T=150°C; 24 h;
参考文献
Journal of Fluorine Chemistry, , vol. 31, p. 151 - 174
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647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
sodium hydroxide in ethanol T=30°C; variation of condition; also with NaOMe; Product distribution;
参考文献
Signe, E.; Blancou, H.; Benefice-Malouet, S.; Itier, J.
Journal of Fluorine Chemistry, 1991 , vol. 54, # 1-3 p. 289
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647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
water; formamide T=150°C; 6 h;
参考文献
Journal of Organic Chemistry, , vol. 58, # 7 p. 1804 - 1811
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647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
water T=140°C; 4.5 h;
参考文献
Journal of Organic Chemistry, , vol. 58, # 7 p. 1804 - 1811
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647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
pyrrolidin-2-one; potassium carbonate 1.) 140 deg C, 6.00 h, 2.) EtOH, CHCl3, 68 deg C, 5 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Brace
Journal of Organic Chemistry, 1996 , vol. 61, # 19 p. 6504 - 6516
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647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
water T=130°C; 7 h; Further byproducts given;
参考文献
Journal of Organic Chemistry, , vol. 61, # 19 p. 6504 - 6516
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647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
water T=141°C; 3 h; Further byproducts given;
参考文献
Journal of Organic Chemistry, , vol. 61, # 19 p. 6504 - 6516
→
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
water; silver nitrate; copper(II) sulfate T=180°C; Gas phase; Conversion of starting material;
参考文献
Daikin Industries, Ltd.
Patent: US6664430 B1, 2003 ;
Location in patent: Page column 8-9 ;
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647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
T=140°C; 7.25 h; Yields of byproduct given;
参考文献
Brace
Journal of Organic Chemistry, 1995 , vol. 60, # 7 p. 2059 - 2071
→
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
potassium carbonate 1.) 140 deg C, 6.00 h, 2.) EtOH, CHCl3, 68 deg C, 5 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Brace
Journal of Organic Chemistry, 1995 , vol. 60, # 7 p. 2059 - 2071
