1-碘-1H,1H,2H,2H-全氟辛烷合成路线 （共 102 条）
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
→
反应条件
4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
DAIKIN INDUSTRIES, LTD.
Patent: EP1757578 A1, 2007 ;
Location in patent: Page/Page column 6-7; 8-9 ;
反应条件
(10H)-phenothiazine in tert-butyl alcohol T=150°C; 6 h;
参考文献
Asahi Glass Company, Limited
Patent: EP1486482 A1, 2004 ;
Location in patent: Page 5; 6 ;
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
→
反应条件
4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
DAIKIN INDUSTRIES, LTD.
Patent: EP1757578 A1, 2007 ;
Location in patent: Page/Page column 6-7; 8-9 ;
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
→
反应条件
4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
DAIKIN INDUSTRIES, LTD.
Patent: EP1757578 A1, 2007 ;
Location in patent: Page/Page column 6-7; 8-9 ;
反应条件
(10H)-phenothiazine in tert-butyl alcohol T=160°C; 9 h;
参考文献
EP1486482 A1, ;
Page 5; 6 ;
→
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
(10H)-phenothiazine in tert-butyl alcohol T=130 - 170°C; 6 - 9 h;
参考文献
EP1486482 A1, ;
Page 5; 6 ;
→
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
pyrrolidin-2-one; potassium carbonate
1.) 140 deg C, 6.00 h, 2.) EtOH, CHCl3, 68 deg C, 5 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Brace
Journal of Organic Chemistry, 1996 , vol. 61, # 19 p. 6504 - 6516
→
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
water
T=130°C; 7 h; Further byproducts given;
参考文献
Brace
Journal of Organic Chemistry, 1996 , vol. 61, # 19 p. 6504 - 6516
→
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
water
T=141°C; 3 h; Further byproducts given;
参考文献
Brace
Journal of Organic Chemistry, 1996 , vol. 61, # 19 p. 6504 - 6516
→
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
potassium carbonate
1.) 140 deg C, 6.00 h, 2.) EtOH, CHCl3, 68 deg C, 5 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Brace
Journal of Organic Chemistry, 1995 , vol. 60, # 7 p. 2059 - 2071
