N,N’-二苯基-N,N’-双(4-甲基苯基)- 4,4’-联苯二胺合成路线 (共 6 条)
反应条件
copper; potassium carbonate; polyethylene glycol in 1,2-dichloro-benzene 22 h; Heating / reflux;
参考文献
Orient Chemical Industries, Ltd.
Patent: EP1553079 A2, 2005 ;
Location in patent: Page/Page column 11 ;
反应条件
1: With Cu(II) perchlorate in acetonitrile T=25°C; 12 h; 2: With potassium carbonate in water; acetonitrile T=25°C; 0.5 h; Further stages.;
参考文献
Sreenath, Kesavapillai; Suneesh, Chettiyam Veettil; Ratheesh Kumar, Venugopal K.; Gopidas, Karical R.
Journal of Organic Chemistry, 2008 , vol. 73, # 8 p. 3245 - 3251
反应条件
copper; potassium carbonate; polyethylene glycol T=90 - 205°C; 17 h; Heating / reflux;
参考文献
Orient Chemical Industries, Ltd.
Patent: EP1553079 A2, 2005 ;
Location in patent: Page/Page column 11-12 ;
反应条件
18-crown-6 ether; copper; potassium carbonate in 1,2-dichloro-benzene T=190°C; Ullmann condensation; 14 h;
参考文献
Zhang, Ya-Dong; Hreha, Richard D.; Jabbour, Ghassan E.; Kippelen, Bernard; Peyghambarian; Marder, Seth R.
Journal of Materials Chemistry, 2002 , vol. 12, # 6 p. 1703 - 1708
反应条件
tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate in tetrahydrofuran T=80°C; 4 h; Inert atmosphere;
参考文献
Scheler, Esther; Strohriegl, Peter
Chemistry of Materials, 2010 , vol. 22, # 4 p. 1410 - 1419
反应条件
iron(III) chloride in benzene T=40°C; 1 h; other solvents; Product distribution;
参考文献
Sato, Hisaya; Kanegae, Aiko; Yamaguchi, Ryoji; Ogino, Kenji; Kurjata, Jan
Chemistry Letters, 1999 , # 1 p. 79 - 80