1,2,3,4-四氢环戊[b]吲哚合成路线 （共 42 条）
反应条件
1: With zinc trifluoromethanesulfonate T=20°C; 1 h; Inert atmosphere; 2: With 1,1'-bis-(diphenylphosphino)ferrocene; tri-ruthenium(0)dodecacarbonyl; toluene-4-sulfonic acid in 1,4-dioxane T=150°C; 22 h; Inert atmosphere;
参考文献
Pena-Lopez, Miguel; Neumann, Helfried; Beller, Matthias
Chemistry - A European Journal, 2014 , vol. 20, # 7 p. 1818 - 1824
反应条件
1: 78 percent / AgF / H2O 2: 56 percent / CO2 / hexamethylphosphoric acid triamide; tetrahydrofuran; acetonitrile / -40 - 20 °C 3: 86 percent / aq. TiCl3; NH4OAc / acetone / 0.25 h / 20 °C View Scheme
参考文献
Organic Letters, , vol. 1, # 4 p. 673 - 676
反应条件
sodium tetrahydroborate
参考文献
Tetrahedron Letters, , vol. 26, # 2 p. 161 - 164
反应条件
in cyclohexane 2.1 h; Irradiation;
参考文献
Wender, Paul A.; Cooper, Christopher B.
Tetrahedron, 1986 , vol. 42, # 11 p. 2985 - 2992
反应条件
2: 100 percent / trifluoroacetic acid / CH2Cl2 / 1.75 h View Scheme
参考文献
Tetrahedron, , vol. 39, # 22 p. 3767 - 3776
反应条件
2: 100 percent / trifluoroacetic acid / CH2Cl2 / 1.75 h View Scheme
参考文献
Tetrahedron, , vol. 39, # 22 p. 3767 - 3776
反应条件
1: 99 percent / Na2CO3 / diethyl ether / 24 h / Ambient temperature 3: 100 percent / trifluoroacetic acid / CH2Cl2 / 1.75 h View Scheme
参考文献
Tetrahedron, , vol. 39, # 22 p. 3767 - 3776
反应条件
1: 74 percent / t-BuOK / dimethylformamide / 0.5 h / 0 °C 2: 44 percent / cyclohexane / 2.1 h / Irradiation View Scheme
参考文献
Tetrahedron, , vol. 42, # 11 p. 2985 - 2992
反应条件
1: 82 percent / CH2Cl2 / 1) -10 deg C, 12 h; 2) room temp. 5 h 2: 74 percent / t-BuOK / dimethylformamide / 0.5 h / 0 °C 3: 44 percent / cyclohexane / 2.1 h / Irradiation View Scheme
参考文献
Tetrahedron, , vol. 42, # 11 p. 2985 - 2992
反应条件
1: trifluoromethanesulfonyl azide; copper(II) sulfate; triethylamine / methanol; dichloromethane; water / 20 °C / Inert atmosphere 2: dirhodium(II) tetraoctanoate / 1,2-dichloro-ethane / 16 h / 70 °C / Inert atmosphere; Molecular sieve View Scheme
参考文献
Angewandte Chemie - International Edition, , vol. 50, # 7 p. 1702 - 1706
