(E)-A,A’-二氟芪合成路线 （共 24 条）
反应条件
T=-196.16°C; UV-irradiationInert atmosphere;
参考文献
Lu, Zhifeng; Moss, Robert A.; Sauers, Ronald R.; Warmuth, Ralf
Organic Letters, 2009 , vol. 11, # 17 p. 3866 - 3869
反应条件
in tetrahydrofuran T=20°C; 2 h; reaction with tetrafluoroethylene; arylation of fluoroolefins by phenyl europium iodide and phenyl ytterbium iodide, prapre in situ from PhI and metallic Eu and Yb; Product distribution;
参考文献
Sigalov, A. B.; Rybakova, L. F.; Beletskaya, I. P.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1983 , vol. 32, # 5 p. 1094
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1983 , # 5 p. 1208
反应条件
1: 1.) NaNO2, aq. HCl / 1.) -10 to -15 deg C, 2.) H2O, acetone, 10-15 deg C, 2 h 2: 92 percent / Cu, pyridine / 2 h / 100 °C View Scheme
参考文献
Kremlev, M. M.; Maznyi, I. S.; Sereda, S. V.; Yagupol'skii, Yu. L.
Journal of Organic Chemistry USSR (English Translation), 1992 , vol. 28, # 5.1 p. 758 - 761
Zhurnal Organicheskoi Khimii, 1992 , vol. 28, # 5 p. 982 - 986
反应条件
1: 1.) NaNO2, aq. HCl / 1.) -10 to -15 deg C, 2.) H2O, acetone, 10-15 deg C, 2 h 2: 92 percent / Cu, pyridine / 2 h / 100 °C View Scheme
参考文献
Kremlev, M. M.; Maznyi, I. S.; Sereda, S. V.; Yagupol'skii, Yu. L.
Journal of Organic Chemistry USSR (English Translation), 1992 , vol. 28, # 5.1 p. 758 - 761
Zhurnal Organicheskoi Khimii, 1992 , vol. 28, # 5 p. 982 - 986
反应条件
iodine; ytterbium 2.) THF, -20 deg C, 8 h; Yield given. Multistep reaction;
参考文献
Sigalov, A. B.; Rybakova, L. F.; Beletskaya, I. P.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1983 , vol. 32, # 5 p. 1094
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1983 , # 5 p. 1208
反应条件
iodine; ytterbium 2.) THF, 20 deg C, 2 h; Yield given. Multistep reaction;
参考文献
Sigalov, A. B.; Rybakova, L. F.; Beletskaya, I. P.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1983 , vol. 32, # 5 p. 1094
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1983 , # 5 p. 1208
参考文献
Meier; Boehler
Chemische Berichte, 1957 , vol. 90, p. 2342
反应条件
ytterbium 1.) THF, 2.) 20 deg C, 8 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Sigalov, A. B.; Beletskaya, I. P.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1988 , vol. 37, p. 364 - 369
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1988 , # 2 p. 445 - 450
反应条件
iodine; ytterbium 1.) ether, THF, -65 deg C, 2.) -20 deg C, 1.5 h, 3.) -20 deg C, 4 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Sigalov, A. B.; Beletskaya, I. P.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1988 , vol. 37, p. 364 - 369
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1988 , # 2 p. 445 - 450
反应条件
(i) XeF2, HF, (ii) KOtBu; Multistep reaction;
参考文献
Gregorcic,A.; Zupan,M.
Journal of Organic Chemistry, 1979 , vol. 44, # 8 p. 1255 - 1258
