Titanium(IV) oxide in neat (no solvent)
Irradiation (UV/VIS); photoassisted catalytic reduction at low temp. (323 K); reaction gas: NO, NH3, Ar and O2, flow rate 100 ml min**-1; irradiation with 300 W ultra-high pressure Xe lamp; detd. by gas chromy.;
参考文献
Tanaka, Tsunehiro; Teramura, Kentaro; Arakaki, Kyoko; Funabiki, Takuzo
Chemical Communications, 2002 , # 22 p. 2742 - 2743
in toluene
toluene soln. of Fe-complex reacted with HCl at 0°C; monitored by IR;
参考文献
Xu, Nan; Campbell, Adam L. O.; Powell, Douglas R.; Khandogin, Jana; Richter-Addo, George B.
Journal of the American Chemical Society, 2009 , vol. 131, # 7 p. 2460 - 2461
phosphate buffer in water
soln. of Na(15)NO2 in H2O and mixt. of NH2OH*HCl with phosphate buffer (pH 7-9) were degassed on the vac. line by successive freeze-pump-thaw cycles, mixed, the reaction was initiated by rotation of the vessel, after 48 h aq. phase was frozen at 194K; collected at 77K;
参考文献
Bonner, Francis T.; Kada, John; Phelan, Kieran G.
Inorganic Chemistry, 1983 , vol. 22, p. 1389 - 1391
potassium phosphate in water
Kinetics; decompn. in anaerobic potassium phosphate buffer, pH=7.0, 25°C, under nitric oxide, 2E-6 mol (15)NO2(1-), 0.6E-6 mol HN2O3(1-); mechanism discussed;; not isolated; detn. in soln. by UV spectroscopy; gas chromatography andmass spectroscopy;;
参考文献
Bazylinski, Dennis A.; Hollocher, Thomas C.
Inorganic Chemistry, 1985 , vol. 24, p. 4285 - 4288
potassium phosphate in water
decompn. in anaerobic potassium phosphate buffer, pH=7.0, 25°C, under nitric oxide, 13.7E-6 mol (15)NO, 0.6E-6 mol HN2O3(1-); mechanism discussed;; not isolated; detn. in soln. by UV spectroscopy; gas chromatography andmass spectroscopy;;
参考文献
Bazylinski, Dennis A.; Hollocher, Thomas C.
Inorganic Chemistry, 1985 , vol. 24, p. 4285 - 4288
