[Cu(II)(tris(2-pyridylmethyl)amine)(OH2)][ClO4]2 in water
Electrolysis; pH = 7, -0.40 V (vs. Ag/AgCl); reaction followed by gas chromy. ((14)N(15)NO : (15)N2O = 1 : 0.63);
参考文献
Komeda, Nobutoshi; Nagao, Hirotaka; Kushi, Yoshinori; Adachi, Gin-ya; Suzuki, Masatatsu; et al.
Bulletin of the Chemical Society of Japan, 1995 , vol. 68, # 2 p. 581 - 589
[Cu(tris(2-pyridylmethyl)amine)(H2O)](2+) in water
Electrolysis; pH = 7, -0.40 V (vs. Ag/AgCl); reaction followed by gas chromy.;
参考文献
Komeda, Nobutoshi; Nagao, Hirotaka; Kushi, Yoshinori; Adachi, Gin-ya; Suzuki, Masatatsu; et al.
Bulletin of the Chemical Society of Japan, 1995 , vol. 68, # 2 p. 581 - 589
Co(3+)*2NH2CH2CH2NH2*3NO2(1-)={Co(NH2CH2CH2NH2)2(NO2)2}NO2 in water
byproducts: water; React. vessel with a closed gas circulation system, in the degassed catalyst soln. in water, at room temp., a gaseous mixture of nitric oxide and ammonia was introduced, vigorous stirring.; Gas phase compn. detd. by gas chromy. (molecular sive 13X for N2 and NO, Chromosrb 103 for N2O and NH3). Isotopic distribution determined by quadrupole mass spectrometry.;
参考文献
Naito, Shuichi; Tamaru, Kenzi
Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1982 , vol. 78, p. 735 - 746
hydrogen in gas
a gaseous mixture of NO, H2, and O2 and He as balance gas passed througha quartz-microreactor at 120-300°C; detected my mass and IR spectroscopies;
参考文献
Savva; Costa; Efstathiou
Kinetics and Catalysis, 2008 , vol. 49, # 5 p. 743 - 747
