1,12-二碳杂十二硼烷合成路线 （共 22 条）
反应条件
water; sodium in ammonia
byproducts: boric acid, I(1-); redn. with 2 mol Na in NH3, processing with H2O;;
参考文献
Stanko, V. I.; Anorova, G. A.; Klimova, T. V.; Klimova, T. P.
Zhurnal Obshchei Khimii, 1970 , vol. 40, p. 2418 - 2427
Zhurnal Obshchei Khimii, 1970 , vol. 40, p. 2432 - 2443
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Gmelin Handbook: B: B-Verb.11, 3, page 38 - 45
反应条件
sodium in ammonia
2 equivalents Na;;
参考文献
Zakharkin, L. I.; Kalinin, V. N.; Snyakin, A. P.
Doklady Akademii Nauk SSSR, 1970 , vol. 190/195, p. 970 - 973
Doklady Akademii Nauk SSSR, 1970 , vol. 195, p. 1357 - 1360
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Gmelin Handbook: B: B-Verb.12, 5.1.14.3, page 219 - 220
反应条件
in gas
gas phase react. of acetylene and B10H14;; mixt. of o-, m- and p-C2B10H12 obtained;;
参考文献
Ditter, J. F.; Klusmann; E. B.; Oakes, J. D.; Williams, R. E.
Inorganic Chemistry, 1970 , vol. 9, p. 889 - 892
反应条件
ammonia; sodium in ammonia
byproducts: NH2(1-); redn. with 2 mol Na in NH3, processing with NH3;;
参考文献
Stanko, V. I.; Anorova, G. A.; Klimova, T. V.; Klimova, T. P.
Zhurnal Obshchei Khimii, 1970 , vol. 40, p. 2418 - 2427
Zhurnal Obshchei Khimii, 1970 , vol. 40, p. 2432 - 2443
Full Text Show Details
Gmelin Handbook: B: B-Verb.11, 3, page 38 - 45
反应条件
methanol; potassium hydroxide
cleavage;
参考文献
Stanko, V. I.; Klimova, T. V.; Beletskaya, I. P.
Doklady Akademii Nauk SSSR, 1974 , vol. 214/219, p. 322 - 324
Doklady Akademii Nauk SSSR, 1974 , vol. 216, p. 329 - 332
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Stanko, V. I.; Klimova, T. V.; Beletskaya, I. P.
Doklady Akademii Nauk SSSR, 1977 , vol. 232/237, p. 350 - 353
Doklady Akademii Nauk SSSR, 1977 , vol. 234, p. 1347 - 1350
反应条件
ammonia; sodium
interconversion;
参考文献
Stanko, V. I.; Brattsev, V. A.; Gol'tyapin, Yu. V.
Doklady Akademii Nauk SSSR, 1976 , vol. 226/231, p. 1243 - 1246
Doklady Akademii Nauk SSSR, 1976 , vol. 231, p. 925 - 928
反应条件
methanol; potassium hydroxide
cleavage;
参考文献
Stanko, V. I.; Klimova, T. V.; Beletskaya, I. P.
Doklady Akademii Nauk SSSR, 1977 , vol. 232/237, p. 350 - 353
Doklady Akademii Nauk SSSR, 1977 , vol. 234, p. 1347 - 1350
反应条件
methanol; potassium hydroxide
Kinetics; 20°C, cleavage;
参考文献
Stanko, V. I.; Klimova, T. V.; Beletskaya, I. P.
Doklady Akademii Nauk SSSR, 1974 , vol. 214/219, p. 322 - 324
Doklady Akademii Nauk SSSR, 1974 , vol. 216, p. 329 - 332
反应条件
methanol; potassium hydroxide
Kinetics; 20°C, cleavage;
参考文献
Stanko, V. I.; Klimova, T. V.; Beletskaya, I. P.
Doklady Akademii Nauk SSSR, 1974 , vol. 214/219, p. 322 - 324
Doklady Akademii Nauk SSSR, 1974 , vol. 216, p. 329 - 332
反应条件
potassium permanganate; sodium in ammonia
redn. with 2 equival. Na in liq. NH3, oxidn. with KMnO4;; 5percent p-carborane, 88percent m-carborane, 7percent 2-, 4-, 5-, 9-I-m-carborane (further product: 5-I-m-carborane);;
参考文献
Stanko, V. I.; Brattsev, V. A.; Gol'typin, Yu. V.; Klimova, T. V.
Zhurnal Obshchei Khimii, 1970 , vol. 40, p. 2207 - 2213
Zhurnal Obshchei Khimii, 1970 , vol. 40, p. 2220 - 2227
Full Text Show Details
Gmelin Handbook: B: B-Verb.11, 3, page 38 - 45
