1,12-二碳杂十二硼烷合成路线 (共 22 条)
反应条件
potassium permanganate; sodium in ammonia
redn. with 2 equival. Na in liq. NH3, oxidn. with KMnO4;; 7percent p-carborane, 42percent m-carborane, 22percent 2-Cl-m-carborane, 2percent 4-Cl-m-carborane, 6percent 5-Cl-m-carborane (further product), 15percent 9-Cl-m-carborane;;
参考文献
Stanko, V. I.; Brattsev, V. A.; Gol'typin, Yu. V.; Klimova, T. V.
Zhurnal Obshchei Khimii, 1970 , vol. 40, p. 2207 - 2213
Zhurnal Obshchei Khimii, 1970 , vol. 40, p. 2220 - 2227
Full Text Show Details
Gmelin Handbook: B: B-Verb.11, 3, page 38 - 45
反应条件
in methanol
Kinetics; hydrolysis;;
参考文献
Stanko, V. I.; Klimova, T. V.; Beletskaya, I. P.
Journal of Organometallic Chemistry, 1973 , vol. 61, p. 191 - 195