in neat (no solvent) inert atmosphere (N2, Ar or high vac.), room temp., equimolar amts. of halosilane/tinhydride, reactn. time 6-8 h; not isolated; IR spectroscopy (identified 95percent SiF3H, trace SiF2H2 and trace SiH4 in product mixt.);
参考文献
D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2177 - 2180
in not given byproducts: H2, CHFCF2; Irradiation (UV/VIS); reaction on UV irradiation in a bomb tube at 25°C;;
参考文献
Clark, H. C.; Furnival, S. G.; Kwon, J. T.
Canadian Journal of Chemistry, 1963 , vol. 41, p. 2889 - 2897
Full Text Show Details
Gmelin Handbook: Sn: Org.Verb.4, 1.2.2.1.1.4, page 97 - 98
Akhtar,M.; Clark,H.C.
Canadian Journal of Chemistry, 1968 , vol. 46, p. 633 - 642
Full Text Show Details
Gmelin Handbook: Sn: Org.Verb.4, 1.2.2.1.1.4, page 97 - 98
Akhtar, M.; Clark, H. C.
Canadian Journal of Chemistry, 1968 , vol. 46, p. 2165 - 2173
Full Text Show Details
Gmelin Handbook: Sn: Org.Verb.4, 1.2.2.1.1.4, page 97 - 98
Akhtar, M.; Clark, H. C.
Canadian Journal of Chemistry, 1968 , vol. 46, p. 2165 - 2173
Full Text Show Details
Gmelin Handbook: Sn: Org.Verb.4, 1.2.2.1.1.4, page 97 - 98
in not given byproducts: H2, CH2CHF; Irradiation (UV/VIS); reaction on UV irradiation in a bomb tube at 25°C;;
参考文献
Clark, H. C.; Furnival, S. G.; Kwon, J. T.
Canadian Journal of Chemistry, 1963 , vol. 41, p. 2889 - 2897
Full Text Show Details
Gmelin Handbook: Sn: Org.Verb.4, 1.2.2.1.1.4, page 97 - 98
in benzene byproducts: (CO)5ReCHCF2, cis-(CO)5ReCFCHF, trans-(CO)5ReCFCHF; Irradiation (UV/VIS); reaction for 48 h at 25°C on UV-irradiation;;
参考文献
Akhtar, M.; Clark, H. C.
Canadian Journal of Chemistry, 1969 , vol. 47, p. 3853 - 3858
Full Text Show Details
Gmelin Handbook: Sn: Org.Verb.4, 1.2.2.1.1.4, page 97 - 98
in neat (no solvent)
addn. 1 equiv. of tinhydride; excess of tinhydride no further reactn.; not isolated; identified 90percent SiF2H2, 5percent SiF3H and 5percent SiH4 in product mixt.;
参考文献
D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2177 - 2180
in neat (no solvent)
inert atmosphere (N2, Ar or high vac.), room temp., equimolar amts. of halosilane/tinhydride, reactn. time 6-8 h; not isolated; IR spectroscopy (identified 95percent SiF3H, trace SiF2H2 and trace SiH4 in product mixt.);
参考文献
D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2177 - 2180
