醋酸(Z)-11-十四烯酯合成路线 （共 59 条）
反应条件
1: 95 percent / H2, quinoline / Lindlar catalyst / pentane / 1 h / -10 °C
2: 95 percent / pyridine / diethyl ether
View Scheme
参考文献
Rossi, Renzo; Carpita, Adriano; Gaudenzi, Loretta; Quirici, Maria Grazia
Gazzetta Chimica Italiana, 1980 , vol. 110, # 4 p. 237 - 246
反应条件
1: p-TsOH / methanol / 2 h / Heating
2: 95 percent / H2, quinoline / Lindlar catalyst / pentane / 1 h / -10 °C
3: 95 percent / pyridine / diethyl ether
View Scheme
参考文献
Rossi, Renzo; Carpita, Adriano; Gaudenzi, Loretta; Quirici, Maria Grazia
Gazzetta Chimica Italiana, 1980 , vol. 110, # 4 p. 237 - 246
反应条件
1: 85percent hydrazine hydrate / butan-1-ol / Heating
2: O2, CuCl / pyridine
3: acetic acid / 10 h / 50 °C
4: H2 / P-2 Ni
View Scheme
参考文献
Oprean, I.; Ciupe, Hilke; Gansca, Lucia; Hodosan, F.
Journal fuer Praktische Chemie (Leipzig), 1987 , vol. 329, # 2 p. 283 - 289
反应条件
1: (AcO)2Cu / acetic acid; H2O / 0.67 h / Heating
2: 85percent hydrazine hydrate / butan-1-ol / Heating
3: O2, CuCl / pyridine
4: acetic acid / 10 h / 50 °C
5: H2 / P-2 Ni
View Scheme
参考文献
Oprean, I.; Ciupe, Hilke; Gansca, Lucia; Hodosan, F.
Journal fuer Praktische Chemie (Leipzig), 1987 , vol. 329, # 2 p. 283 - 289
反应条件
1: O2, CuCl / pyridine
2: acetic acid / 10 h / 50 °C
3: H2 / P-2 Ni
View Scheme
参考文献
Oprean, I.; Ciupe, Hilke; Gansca, Lucia; Hodosan, F.
Journal fuer Praktische Chemie (Leipzig), 1987 , vol. 329, # 2 p. 283 - 289
反应条件
1: 85 percent / lithium diisopropylamide / tetrahydrofuran / 0.25 h / -78 °C
2: 71 percent / tetrahydrofuran / -79 °C
3: acetic acid / 80 °C
View Scheme
参考文献
Macdonald, Timothy L.; Narayanan, Amirthalingam B.; O'Dell, Dale E.
Journal of Organic Chemistry, 1981 , vol. 46, # 7 p. 1504 - 1506
反应条件
1: 85 percent / PBr3 / benzene / 5 h / Ambient temperature
2: 22 g / acetonitrile / 8 h / Heating
3: 1.) potassium tert-butanolate / 1.) DMF, 20 deg C, 3h, 2.) 5h
4: LiAlH4 / diethyl ether / 3 h / Heating
5: pyridine / 10 h / Ambient temperature
View Scheme
参考文献
Dzhemilev, U. M.; Balezina, G. G.; Volkova, L. A.; Krivonogov, V. P.; Tolstikov, G. A.
Chemistry of Natural Compounds, 1980 , vol. 16, # 1 p. 82 - 85
Khimiya Prirodnykh Soedinenii, 1980 , vol. 16, # 1 p. 97 - 102
反应条件
1: LiAlH4 / diethyl ether / 3 h / Heating
2: pyridine / 10 h / Ambient temperature
View Scheme
参考文献
Dzhemilev, U. M.; Balezina, G. G.; Volkova, L. A.; Krivonogov, V. P.; Tolstikov, G. A.
Chemistry of Natural Compounds, 1980 , vol. 16, # 1 p. 82 - 85
Khimiya Prirodnykh Soedinenii, 1980 , vol. 16, # 1 p. 97 - 102
反应条件
1: 72 percent / dipotassium diazenedicarboxylate / pyridine; methanol; acetic acid / 25 h
2: 1.) tetrakis<triphenylphosphine>-palladium / 1.) benzene, room temp., 15 min, 2.) room temp., overnight
3: p-toluenesulfonic acid monohydrate / methanol; H2O / 2 h / 50 °C
4: pyridine / 1.) 18 h, 0 deg C, 2.) 18 h, room temp.
View Scheme
参考文献
Michelot, Didier
Synthesis, 1983 , # 2 p. 130 - 134
反应条件
1: 1.) tetrakis<triphenylphosphine>-palladium / 1.) benzene, room temp., 15 min, 2.) room temp., overnight
2: p-toluenesulfonic acid monohydrate / methanol; H2O / 2 h / 50 °C
3: pyridine / 1.) 18 h, 0 deg C, 2.) 18 h, room temp.
View Scheme
参考文献
Michelot, Didier
Synthesis, 1983 , # 2 p. 130 - 134
