in neat (no solvent) TiCl4 was slowly added to tetraisopropoxytitanium at 0°C, then the mixt. allowed to warm up to room temp.;; distn. (61-65°C/0.1 Torr), the purity of the product exceeds 98 percent, it solidified at room temp., but could be easily liquified to handle;;

暂无反应条件数据

bis(η3-allyl-μ-chloropalladium(II)) in diethyl ether; benzene reaction of soln. of PhTi(i-OPr)3 in ether (obtained from reaction of PhLi with ClTi(i-OPr)3 in ether) with soln. of allylchloride and (C3H5PdCl)2 in benzene at 20°C under Ar;; not isolated;;

bis(η3-allyl-μ-chloropalladium(II)) in diethyl ether; benzene reaction of soln. of PhTi(i-OPr)3 in ether (obtained from reaction of PhLi with ClTi(i-OPr)3 in ether) with soln. of chloride and (C3H5PdCl)2 in benzene at 20°C under Ar;; not isolated;;

暂无反应条件数据

暂无反应条件数据

in diethyl ether byproducts: LiCl; an abs. etheric soln. of ClTi(OCHMe2)3 was stirred at -40°C under N2, then CH3Li was added and the mixt. allowed to warm up to room temp. within 1.5 h;; after evapn. of the solvent in vac., the product was distd. directly from the residual LiCl at 48-53°C and 0.01 Torr;;

n-butyllithium in tetrahydrofuran ligand reacted with n-BuLi (1.1 equiv.) in THF at -78°C; treated with Ti compd. (1.1 equiv.) at -78°C; warmed to room temp.; not isolated; detd. by NMR spectra;

n-butyllithium in tetrahydrofuran ligand reacted with n-BuLi (1.1 equiv.) in THF at -78°C; treated with Ti compd. (1.1 equiv.) at -78°C; warmed to room temp.; not isolated; detd. by NMR spectra;