2,2-二甲基-1,3-二氢茚合成路线 （共 9 条）
反应条件
triethylsilane; trifluoroacetic acid
T=50°C; 20 h;
参考文献
Popova, O. K.; Pernes, Z. N.; Katinkin, M. I.; Markosyan, S. M.; Kopteva, N. I.; et al.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1981 , vol. 30, # 9 p. 1709 - 1711
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1981 , vol. 30, # 9 p. 2084 - 2087
反应条件
1: aq. HF
2: (reduction)
View Scheme
参考文献
Warrick,P.; Saunders,W.H.
Journal of the American Chemical Society, 1962 , vol. 84, p. 4095 - 4100
参考文献
Warrick,P.; Saunders,W.H.
Journal of the American Chemical Society, 1962 , vol. 84, p. 4095 - 4100
反应条件
methanol
Irradiation; Further byproducts given;
参考文献
Pincock, J. A.; Wedge, P. J.
Journal of Organic Chemistry, 1995 , vol. 60, # 13 p. 4067 - 4076
反应条件
1: (i) NaNH2, (ii) /BRN= 635994/
2: KOH, N2H4*H2O / bis-(2-hydroxy-ethyl) ether / Heating
View Scheme
参考文献
Braude,E.A. et al.
Journal of the Chemical Society, 1960 , p. 3123 - 3132
反应条件
1: (i) NaNH2, (ii) /BRN= 635994/
2: (i) NaNH2, (ii) /BRN= 635994/
3: KOH, N2H4*H2O / bis-(2-hydroxy-ethyl) ether / Heating
View Scheme
参考文献
Braude,E.A. et al.
Journal of the Chemical Society, 1960 , p. 3123 - 3132
反应条件
1: NaOAc, aq. AcOH / (electrolysis)
2: KOtBu
3: H2 / Pd-C
View Scheme
参考文献
Sternerup,H.
Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1974 , vol. 28, p. 969 - 980
反应条件
Irradiation; Further byproducts given;
参考文献
Pincock, J. A.; Wedge, P. J.
Journal of Organic Chemistry, 1995 , vol. 60, # 13 p. 4067 - 4076
反应条件
Irradiationalso for corresponding 5- or 6-methoxy esters; MechanismRate constantQuantum yield;
参考文献
Pincock, J. A.; Wedge, P. J.
Journal of Organic Chemistry, 1995 , vol. 60, # 13 p. 4067 - 4076
