6-叠氮-6-脱氧-D-葡萄糖合成路线 （共 13 条）
反应条件
hydrogenchloride 1.5 h; Ambient temperature;
参考文献
Liebigs Annalen der Chemie, , # 11 p. 1982 - 1993
反应条件
trifluoroacetic acid in water
T=20°C; 1 h;
参考文献
Blanco, Jose L. Jimenez; Bootello, Purificacion; Mellet, Carmen Ortiz; Gallego, Ricardo Gutierrez; Fernandez, Jose M. Garcia
Chemical Communications (Cambridge, United Kingdom), 2004 , # 1 p. 92 - 93
参考文献
Griffith, Byron R.; Krepel, Candace; Fu, Xun; Blanchard, Sophie; Ahmed, Aqeel; Edmiston, Charles E.; Thorson, Jon S.
Journal of the American Chemical Society, 2007 , vol. 129, # 26 p. 8150 - 8155
反应条件
Amberlite IR 120 in water
T=40°C;
参考文献
Raadt, Anna de; Stuetz, Arnold E.
Tetrahedron Letters, 1992 , vol. 33, # 2 p. 189 - 192
反应条件
lithium azide in water; N,N-dimethyl-formamide
T=80°C; 1 h;
参考文献
Chaveriat, Ludovic; Stasik, Imane; Demailly, Gilles; Beaupere, Daniel
Tetrahedron Asymmetry, 2006 , vol. 17, # 9 p. 1349 - 1354
反应条件
1: 70 percent / pyridine
2: 98 percent / NaN3 / acetone; H2O
3: 50 percent / aq. H2SO4
View Scheme
参考文献
Griffith, Byron R.; Krepel, Candace; Fu, Xun; Blanchard, Sophie; Ahmed, Aqeel; Edmiston, Charles E.; Thorson, Jon S.
Journal of the American Chemical Society, 2007 , vol. 129, # 26 p. 8150 - 8155
反应条件
1: 98 percent / NaN3 / acetone; H2O
2: 50 percent / aq. H2SO4
View Scheme
参考文献
Griffith, Byron R.; Krepel, Candace; Fu, Xun; Blanchard, Sophie; Ahmed, Aqeel; Edmiston, Charles E.; Thorson, Jon S.
Journal of the American Chemical Society, 2007 , vol. 129, # 26 p. 8150 - 8155
反应条件
magnesium chloride; manganese (II) chloride in water
T=50°C; 24 h; enzyme glucose isomerase;
参考文献
Durrwachter, John R.; Wong, Chi-Huey
Journal of Organic Chemistry, 1988 , vol. 53, # 18 p. 4175 - 4181
反应条件
1: CCl4, PPh3, pyridine
2: 81 percent / NaN3 / dimethylformamide / 16 h / 100 °C
3: 64 percent / Amberlite IR 120 / H2O / 40 °C
View Scheme
参考文献
Raadt, Anna de; Stuetz, Arnold E.
Tetrahedron Letters, 1992 , vol. 33, # 2 p. 189 - 192
反应条件
1: 56 percent / triphenylphosphine; carbon tetrabromide / dimethylformamide / 1.5 h / 50 °C
2: 70 percent / lithium azide / dimethylformamide; H2O / 1 h / 80 °C
View Scheme
参考文献
Chaveriat, Ludovic; Stasik, Imane; Demailly, Gilles; Beaupere, Daniel
Tetrahedron Asymmetry, 2006 , vol. 17, # 9 p. 1349 - 1354
