2-苯基-1,2-环氧丙烷合成路线 （共 116 条）
反应条件
methyllithium; iron(III) chloride in diethyl ether from -78 deg C up to 20 deg C, 18 h;
参考文献
Chemische Berichte, , vol. 127, # 4 p. 659 - 666
反应条件
Amberlite IRA-400; borohydride form; copper(II) sulfate in methanol T=20°C; Reduction; 3 h;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 70, # 5 p. 1101 - 1107
反应条件
in toluene T=50°C; effect of the nickel catalyst and reaction temp.; Product distribution;
参考文献
Miyashita, Akira; Shimada, Takeshi; Sugawara, Atsushi; Nohira, Hiroyuki
Chemistry Letters, 1986 , p. 1323 - 1326
反应条件
n-butyllithium; boron trifluoride-diethyl ether complex
1.) HMPA; Yield given. Multistep reaction;
参考文献
Murayama, Eigoro; Kikuchi, Toshihiro; Sasaki, Kotaro; Sootome, Norio; Sato, Tadashi
Chemistry Letters, 1984 , p. 1897 - 1900
反应条件
water
1) Et2O, -78 deg C to 20 deg C, 18 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Kauffmann, Thomas; Neiteler, Christel; Robbe, Sonja
Chemische Berichte, 1992 , vol. 125, # 11 p. 2409 - 2418
反应条件
water
1) Et2O, -78 deg C to 20 deg C, 18 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Kauffmann, Thomas; Neiteler, Christel; Robbe, Sonja
Chemische Berichte, 1992 , vol. 125, # 11 p. 2409 - 2418
反应条件
(S)-La-Li3-(binaphthoxide)3; tris(2,4,6-trimethoxyphenyl)phosphine oxide in tetrahydrofuran; hexane
T=45°C; 48 h; Molecular sieve; optical yield given as percent eeenantioselective reaction;
参考文献
Sone, Toshihiko; Lu, Gang; Matsunaga, Shigeki; Shibasaki, Masakatsu
Angewandte Chemie - International Edition, 2009 , vol. 48, # 9 p. 1677 - 1680
反应条件
Aspergillus niger LCP 521 epoxide hydrolase in N,N-dimethyl-formamide
T=27°C; Hydrolysis; pH=8.0; Product distribution; Further Variations:Reagents;
参考文献
Cleij; Archelas; Furstoss
Journal of Organic Chemistry, 1999 , vol. 64, # 14 p. 5029 - 5035
反应条件
1: boron trifluoride diethyl etherate / tetrahydrofuran / 25 °C
2: triethylamine / |Reflux
3: N-bromosuccinmide; C26H27N3OS / chloroform; hexane / 15 h / -50 °C / |Schlenk technique; |Inert atmosphere
View Scheme
参考文献
Tan, Chong Kiat; Er, Jun Cheng; Yeung, Ying-Yeung
Tetrahedron Letters, 2014 , vol. 55, # 6 p. 1243 - 1246
反应条件
NH2-MIL-101(Al) metal-organic framework in acetonitrile
T=60°C;
参考文献
Srirambalaji, Renganathan; Hong, Soonsang; Natarajan, Ramalingam; Yoon, Minyoung; Hota, Raghunandan; Kim, Yonghwi; Ho Ko, Young; Kim, Kimoon
Chemical Communications, 2012 , vol. 48, # 95 p. 11650 - 11652
