1,1'-(2,4-吡啶二基)二乙酮合成路线 （共 8 条）
反应条件
NH4S2O8; silver nitrate; trifluoroacetic acid in dichloromethane; water T=40°C; 2.5 h;
参考文献
Fontana, Francesca; Minisci, Francesco; Barbosa, Maria Claudia Nogueira; Vismara, Elena
Journal of Organic Chemistry, 1991 , vol. 56, # 8 p. 2866 - 2869
反应条件
in tetrahydrofuran; diethyl ether T=0°C; 1 h;
参考文献
West Jr.; Silverman; Dougherty
Journal of the American Chemical Society, 1996 , vol. 118, # 6 p. 1452 - 1463
反应条件
1: With sodium ethanolate in ethyl acetate T=70 - 80°C; 2 h; 2: With hydrogenchloride in ethyl acetate 4 h; Heating;
参考文献
Attia, A.; El-Salam, O. I. Abd; Youssef, T. E.
Egyptian Journal of Chemistry, 2000 , vol. 43, # 5 p. 351 - 362
反应条件
1: SOCl2 / toluene / 16 h / Heating 2: pyridine / CH2Cl2 / 0.75 h / 0 - 20 °C 3: 71 percent / tetrahydrofuran; diethyl ether / 1 h / 0 °C View Scheme
参考文献
West Jr.; Silverman; Dougherty
Journal of the American Chemical Society, 1996 , vol. 118, # 6 p. 1452 - 1463
反应条件
potassium peroxomonosulphate; silver nitrate in water 2 h; Heating; Yield given. Yields of byproduct given;
参考文献
Chianelli, D.; Testaferri, L.; Tiecco, M.; Tingoli, M.
Tetrahedron, 1982 , vol. 38, # 5 p. 657 - 663
反应条件
formic acid; zinc
T=160 - 165°C; 10 h;
参考文献
Attia, A.; El-Salam, O. I. Abd; Youssef, T. E.
Egyptian Journal of Chemistry, 2000 , vol. 43, # 5 p. 351 - 362
反应条件
sulfuric acid; Titanium(IV) oxide
T=20 - 30°C; 10 h; Electrochemical reaction;
参考文献
Attia, A.; El-Salam, O. I. Abd; Youssef, T. E.
Egyptian Journal of Chemistry, 2000 , vol. 43, # 5 p. 351 - 362
反应条件
1: 26 percent / TiO2; 35 percent aq. H2SO4 / 10 h / 20 - 30 °C / Electrochemical reaction
2: 71 percent / Zn; 80 percent HCOOH / 10 h / 160 - 165 °C
View Scheme
参考文献
Attia, A.; El-Salam, O. I. Abd; Youssef, T. E.
Egyptian Journal of Chemistry, 2000 , vol. 43, # 5 p. 351 - 362
