反应条件
Stage #1: <a href="#" onclick="return RXDsubstances(event, this, '1697100', constants.ctx, '0')">3,3-dimethylbut-1-yne</a> <b>With</b> <a href="#" onclick="return RXDsubstances(event, this, '13241694', constants.ctx, '0')">polymethylhydrosiloxane</a>; <a href="#" onclick="return RXDsubstances(event, this, '1577564', constants.ctx, '0')">trifuran-2-yl-phosphane</a>; <a href="#" onclick="return RXDsubstances(event, this, '3600469', constants.ctx, '0')">Me<sub>3</sub>SnF</a>; <a href="#" onclick="return RXDsubstances(event, this, '11343411', constants.ctx, '0')">tris-(dibenzylideneacetone)dipalladium<sup>(0)</sup></a>; <a href="#" onclick="return RXDsubstances(event, this, '3570522', constants.ctx, '0')">tetrabutyl ammonium fluoride</a> <b>in</b> <a href="#" onclick="return RXDsubstances(event, this, '102391', constants.ctx, '0')">tetrahydrofuran</a> <br />T=20°C; 2 h; <br />Stage #2: <a href="#" onclick="return RXDsubstances(event, this, '385668', constants.ctx, '0')">pivaloyl chloride</a> <b>in</b> <a href="#" onclick="return RXDsubstances(event, this, '102391', constants.ctx, '0')">tetrahydrofuran</a> <br />T=65°C; Stille reaction; 4 h; <br />
参考文献
Lee, Kyoungsoo; Gallagher, William P.; Toskey, Elli A.; Chong, Wenzheng; Maleczka Jr., Robert E. Journal of Organometallic Chemistry, 2006 , vol. 691, # 8 p. 1462 - 1465
